3-甲氧基-1,7-辛二烯合成路线 （共 22 条）
反应条件
palladium(II) chloride in methanol
参考文献
National Distillers and Chemical Corporation
Patent: US4721820 A1, 1988 ;
反应条件
1: With tris(4-methoxyphenyl)-phosphine; tris-(dibenzylideneacetone)dipalladium(0)
T=25°C; 0.166667 h;
2: methanol; buta-1,3-diene T=60°C; 4 h; Product distribution / selectivity;
参考文献
Edwards, Charles Lee
Patent: US2005/38305 A1, 2005 ;
Location in patent: Page/Page column 6 ;
参考文献
Beger,J.; Reichel,H.
Journal fuer Praktische Chemie (Leipzig), 1973 , vol. 315, p. 1067 - 1076
反应条件
N-ethyl-N-hydroxyethylamine; palladium diacetate; triphenylphosphine in anhydrous butyl ether; water; 2-methyl cyclohexane
T=90°C; 2 h; Product distribution / selectivity;
参考文献
DOW GLOBAL TECHNOLOGIES INC.; BRIGGS, John; PATTON, Jasson; VERMAIRE-LOUW, Sonet; MARGL, Peter; HAGEN, Henk; BEIGZADEH, Daryoosh
Patent: WO2010/19360 A2, 2010 ;
Location in patent: Page/Page column 16-20 ;
反应条件
triphenylphosphine; bis(dibenzylideneacetone)-palladium(0)
T=80°C; 20 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Neibecker, Denis; Poirier, Jacques; Tkatchenko, Igor
Journal of Organic Chemistry, 1989 , vol. 54, # 10 p. 2459 - 2462
反应条件
2-methallyloxyphosphonium PF6 salt; bis(dibenzylideneacetone)-palladium(0) in toluene
T=80°C; 20 h; Yield given;
参考文献
Neibecker, Denis; Poirier, Jacques; Tkatchenko, Igor
Journal of Organic Chemistry, 1989 , vol. 54, # 10 p. 2459 - 2462
反应条件
acetic acid; triphenylphosphine; bis(acetylacetonato) palladium in anhydrous butyl ether; 2-methyl cyclohexane
Product distribution / selectivity;
参考文献
DOW GLOBAL TECHNOLOGIES LLC; BRIGGS, John R.; PATTON, Jasson T.; BEIGZADEH, Daryoosh; MARGL, Peter M.; HAGEN, Henk; VERMAIRE-LOUW, Sonet
Patent: WO2012/87686 A1, 2012 ;
Location in patent: Page/Page column 14-16 ;
反应条件
4-tert-butyl-benzoic acid; Pd(OAc)2dppb in methoxybenzene
T=140°C; P=37503.8 Torr; 16 h; Product distribution; Further Variations:CatalystsReagentsTemperaturesReaction partners;
参考文献
Beller, Matthias; Krotz, Andreas; Baumann, Wolfgang
Advanced Synthesis and Catalysis, 2002 , vol. 344, # 5 p. 517 - 524
反应条件
triethylamine; triphenylphosphine; palladium diacetate
T=90°C; 2.5 h; Product distribution; Further Variations:ReagentsTemperaturesratio;
参考文献
Vollmueller, Frank; Maegerlein, Wolfgang; Klein, Susanne; Krause, Jochen; Beller, Matthias
Advanced Synthesis and Catalysis, 2001 , vol. 343, # 1 p. 29 - 33
反应条件
1-butylpyridinium hexafluorophosphate; triphenylphosphine; palladium diacetate
T=85°C; 5 h; Product distribution / selectivity;
参考文献
Celanese Chemicals Europe GmbH
Patent: EP1201634 A1, 2002 ;
Location in patent: Page 17-18 ;
