1,1,1-三氟-2-(三氟甲氧基)乙烷合成路线 （共 10 条）
反应条件
bromine trifluoride T=35 - 45°C; Fluorination; 6 h;
参考文献
Hudlicky, Tomas; Duan, Caiming; Reed, Josephine W.; Yan, Fengyang; Hudlicky, Milos; Endoma, Mary Ann; Eger II, Edmond I.
Journal of Fluorine Chemistry, 2000 , vol. 102, # 1-2 p. 363 - 367
反应条件
hydrogen fluoride; boron trifluoride T=150°C; Etherification; 14 h;
参考文献
Petrov, Viacheslav A.; Davidson, Fred
Journal of Fluorine Chemistry, 1999 , vol. 95, # 1-2 p. 5 - 14
反应条件
sulfur(IV) fluoride T=150 - 200°C; Product distribution / selectivity;
参考文献
E. I. du Pont de Nemours and Company
Patent: US6905630 B2, 2005 ;
Location in patent: Page/Page column 5 ;
反应条件
in monofluoro-trichloromethane T=-160 - 22°C; 20 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Johri, Kamalesh K.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1983 , vol. 48, # 2 p. 242 - 250
反应条件
fluorine; NAF Further byproducts given;
参考文献
Sekiya, Akira; Ueda, Kunimasa
Chemistry Letters, 1990 , # 4 p. 609 - 612
反应条件
20 h; -111 deg C to 20 deg C;
参考文献
Sekiya, Akira; Ueda, Kunimasa
Chemistry Letters, 1990 , # 4 p. 609 - 612
反应条件
in monofluoro-trichloromethane T=-105°C; competition with ClFC=CFCl and H2C=CF2, relative addition rates and orientation ratios; Rate constantProduct distribution;
参考文献
Navarrini, W.; Russo, A.; Tortelli, V.
Journal of Organic Chemistry, 1995 , vol. 60, # 20 p. 6441 - 6443
反应条件
fluorine; NAF 20 h; -111 deg C to 20 deg C;
参考文献
Sekiya, Akira; Ueda, Kunimasa
Chemistry Letters, 1990 , # 4 p. 609 - 612
反应条件
fluorine; NAF
20 h; -111 deg C to 20 deg C; also without NaF;
参考文献
Sekiya, Akira; Ueda, Kunimasa
Chemistry Letters, 1990 , # 4 p. 609 - 612
反应条件
fluorine; NAF
20 h; -111 deg C to 20 deg C;
参考文献
Sekiya, Akira; Ueda, Kunimasa
Chemistry Letters, 1990 , # 4 p. 609 - 612
