1: With n-butyllithium in tetrahydrofuran; hexane T=-78°C; Inert atmosphere; 2: With boric acid trimethyl ester in tetrahydrofuran; hexane T=-78°C; 2 h; 3: With hydrogenchloride; water in tetrahydrofuran; hexane pH=5 - 6;
参考文献
Wu, Wenting; Cheng, Chuanhui; Wu, Wanhua; Guo, Huimin; Ji, Shaomin; Song, Peng; Han, Keli; Zhao, Jianzhang; Zhang, Xin; Wu, Yubo; Du, Guotong
European Journal of Inorganic Chemistry, 2010 , # 29 p. 4683 - 4696
nBuLi; HCl in tetrahydrofuran; hexane (Ar), soln. of 4-bromotriphenylamine in THF cooled to -78°C, slowly treated with nBuLi in hexane, stirred at -78°C for 1 h, treated with 1.2 equiv. of B(OMe)3, stirred for 2 h; warmed to room temp., pH adjusted to 5-6 (aq.HCl), wxtd.(CH2Cl2), org. phase washed (H2O, brine), dried (Na2SO4), evapd., elem. anal.;
参考文献
Wu, Wenting; Cheng, Chuanhui; Wu, Wanhua; Guo, Huimin; Ji, Shaomin; Song, Peng; Han, Keli; Zhao, Jianzhang; Zhang, Xin; Wu, Yubo; Du, Guotong
European Journal of Inorganic Chemistry, 2010 , # 29 p. 4683 - 4696
1: 4-(N,N-diphenylamino)-bromobenzene With n-butyllithium in tetrahydrofuran; toluene T=-70°C; 1 h; 2: tri-isopropoxy-borane in tetrahydrofuran; toluene T=20°C; 2 h; 3: With hydrogenchloride; water in tetrahydrofuran; toluene T=20°C; 2 h;
1: 4-(N,N-diphenylamino)-bromobenzene With n-butyllithium in tetrahydrofuran; hexane T=-80°C; 1 h; 2: boric acid trimethyl ester in tetrahydrofuran; hexane T=20°C; Hexane; 15 h; 3: With hydrogenchloride in tetrahydrofuran; water
参考文献
SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Patent: WO2007/125934 A1, 2007 ;
Location in patent: Page/Page column 192-193 ;
