1: 1.) n-BuLi / 1.) THF, 0 deg C, 12 h, 2.) 0 deg C, 1 h; room temperature, 2 h 2: 65 percent / acetonitrile / 1.) room temperature, 1 h, 2.) reflux, 1 h 3: 1.) t-Bu4NF / 2.) palladium charcoal / 1.) MeCN, room temperature, 1 h, 2.) tetralin, reflux, 26 h View Scheme

1: 65 percent / acetonitrile / 1.) room temperature, 1 h, 2.) reflux, 1 h 2: 1.) t-Bu4NF / 2.) palladium charcoal / 1.) MeCN, room temperature, 1 h, 2.) tetralin, reflux, 26 h View Scheme

1: 1.) n-BuLi, 2.) Et3N / 1.) Et2O, room temperatutre, 22 h, 2.) room temperature, 4 h 2: 1.) n-BuLi / 1.) THF, 0 deg C, 12 h, 2.) 0 deg C, 1 h; room temperature, 2 h 3: 65 percent / acetonitrile / 1.) room temperature, 1 h, 2.) reflux, 1 h 4: 1.) t-Bu4NF / 2.) palladium charcoal / 1.) MeCN, room temperature, 1 h, 2.) tetralin, reflux, 26 h View Scheme

tetra(tert-butyl)-ammonium fluoride; palladium on activated charcoal 1.) MeCN, room temperature, 1 h, 2.) tetralin, reflux, 26 h; Yield given. Multistep reaction;

diethyl ether

暂无反应条件数据

1: (i) SOCl2, (ii) NH3 2: SOCl2 View Scheme

1: H2SO4 2: P2O5, H3PO4 View Scheme