顺式-7-十二碳烯-1-醇合成路线 （共 41 条）
反应条件
1: KOH / methanol / (electrolysis)
2: LiAlH4
View Scheme
参考文献
Seidel,W. et al.
Chemische Berichte, 1977 , vol. 110, p. 3544 - 3552
反应条件
1: 80 percent / PBr3, pyridine / diethyl ether / 1 h / 5 °C
View Scheme
参考文献
Tolstikov, G. A.; Odinokov, V. N.; Galeeva, R. I.; Bakeeva, R. S.; Akhunova, V. R.
Chemistry of Natural Compounds, 1982 , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 2 p. 239 - 245
反应条件
1: 54 percent / KOH / H2O; methanol / 24 h / Ambient temperature
2: 80 percent / PBr3, pyridine / diethyl ether / 1 h / 5 °C
View Scheme
参考文献
Tolstikov, G. A.; Odinokov, V. N.; Galeeva, R. I.; Bakeeva, R. S.; Akhunova, V. R.
Chemistry of Natural Compounds, 1982 , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 2 p. 239 - 245
反应条件
1: 2.) PCC
2: n-BuLi / toluene / 2 h / 25 °C
3: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: 90 percent / acetonitrile / 24 h / Heating
2: NaOEt / tetrahydrofuran / 1 h / 25 °C
3: n-BuLi / toluene / 2 h / 25 °C
4: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: n-BuLi / toluene / 2 h / 25 °C
2: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: n-BuLi / toluene / 2 h / 25 °C
2: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: Baeyer-Villiger oxidation
2: 2.) PCC
3: n-BuLi / toluene / 2 h / 25 °C
4: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: 81 percent / sodium metaperiodate / ethanol; H2O
2: NaH / dimethylsulfoxide; tetrahydrofuran
View Scheme
参考文献
Chattopadhyay, A.; Mamdapur, V. R.; Chadha, M. S.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 2 p. 158 - 159
反应条件
1: 55 percent / Li2CuCl4 / tetrahydrofuran / 3 h / -10 °C
2: 54 percent / pyridinium p-toluenesulfonate / methanol / 6 h / 55 °C
View Scheme
参考文献
Trehan; Vig; Singh; Sharma; Kad
Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, 1990 , vol. 29, # 6 p. 518 - 520
