1-(三甲基硅氧基)环戊烯合成路线 （共 155 条）
反应条件
zinc(II) chloride in ethyl acetate
T=20 - 25°C; 18 h; Title compound not separated from byproducts;
参考文献
Makin, S. M.; Kruglikova, R. I.; Popova, T. P.; Tagirov, T. K.
Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, # 4 p. 630 - 634
Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 4 p. 723 - 727
反应条件
1: ethylene oxide / -15 °C
2: DBN / CH2Cl2 / -78 °C
View Scheme
参考文献
Paterson, Ian
Tetrahedron, 1988 , vol. 44, # 13 p. 4207 - 4220
反应条件
α-cyclohexylcyclohexanemethanamine; trimethylsilyl iodide in acetonitrile
4 h; Ambient temperature;
参考文献
Hosomi, Akira; Iijima, Susumu; Sakurai, Hideki
Tetrahedron Letters, 1982 , vol. 23, # 5 p. 547 - 550
反应条件
2,6-dichloro-benzonitrile
1) ethylene oxide / -15 deg C / photolysis 2) CH2Cl2 / -23 deg C; Yield given. Multistep reaction;
参考文献
Block, Eric; Aslam, Mohammad; Iyer, Rajeshwari; Hutchinson, John
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3664 - 3666
反应条件
1: 1.) methyl cyanide, 2.) Me3NO / 1.) room temperature, 3 h, 2.) C6H6, reflux, 2 h
2: DDQ / diethyl ether / 0.5 h / Ambient temperature
View Scheme
参考文献
Bovicelli, P; Mincione, E.
Synthetic Communications, 1988 , vol. 18, # 16-17 p. 2037 - 2050
反应条件
TASF-(Et) in tetrahydrofuran
T=-78°C; 4 h;
参考文献
Noyori, R.; Nishida, I.; Sakata, J.
Journal of the American Chemical Society, 1983 , vol. 105, # 6 p. 1598 - 1608
反应条件
1,2-bis-(diphenylphosphino)ethane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in tetrahydrofuran
12 h; Heating;
参考文献
Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao
Chemistry Letters, 1983 , p. 1325 - 1326
反应条件
[VO(OEt)Cl2] in dichloromethane
T=-75°C;
参考文献
Hirao, Toshikazu; Fujii, Takashi; Ohshiro, Yoshiki
Tetrahedron, 1994 , vol. 50, # 34 p. 10207 - 10214
反应条件
[Pd(1,2-bis(diphenylphosphino)ethane)(OAc)2] in acetonitrile
T=80°C; var. catalyst, solvent;; Product distribution;
参考文献
Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao; Kataoka, Hideaki
Chemistry Letters, 1984 , p. 1133 - 1136
反应条件
Pd/SiO2 in N,N-dimethyl-formamide
T=59.9°C; 24 h; various solvents, various reagents; Product distribution;
参考文献
Baba, T.; Nakano, K.; Nishiyama, S.; Tsurya, S.; Masai, M.
Journal of the Chemical Society, Chemical Communications, 1990 , # 4 p. 348 - 349
