1: NSC 82303 With sodium hydride in DMF (N,N-dimethyl-formamide) T=0 - 20°C; 1.5 h; 2: 4-fluorobenzaldehyde in DMF (N,N-dimethyl-formamide) T=-10 - 20°C; 0.75 h;

PdCl2(C3H3N2(CH3))(C3H2N2(C6H3(C3H7)2)2); tetrabutylammomium bromide; caesium carbonate T=140°C; Heck Reaction; 12 h; Sealed tube;