4-氯-alpha,alpha-二甲基苄醇合成路线 （共 26 条）
参考文献
Journal of the American Chemical Society, , vol. 70, p. 1177
反应条件
hydrogen; palladium on activated charcoal in ethanol T=50°C; var. solv.: isooctane; Product distribution;
参考文献
Marques, Carlos Alberto; Selva, Maurizio; Tundo, Pietro
Gazzetta Chimica Italiana, 1996 , vol. 126, # 6 p. 317 - 328
反应条件
perchloric acid in acetic acid Ambient temperature;
参考文献
Baciocchi, Enrico; Bietti, Massimo; Salamone, Michela; Steenken, Steen
Journal of Organic Chemistry, 2002 , vol. 67, # 7 p. 2266 - 2270
反应条件
1: 1.) SOCl2; 2.) HCl gas, 3.) ZnCl2 / 1.) pyridine 2: 8N hydrochloric acid / H2O / 70-80 deg C, 0.5 h; reflux, 0.5 h View Scheme
参考文献
Sato, Kazuo; Honma, Toyokuni; Sugai, Soji
Agricultural and Biological Chemistry, 1985 , vol. 49, # 12 p. 3563 - 3568
反应条件
hydrogenchloride; thionyl chloride; zinc(II) chloride
1.) pyridine; Multistep reaction;
参考文献
Sato, Kazuo; Honma, Toyokuni; Sugai, Soji
Agricultural and Biological Chemistry, 1985 , vol. 49, # 12 p. 3563 - 3568
反应条件
1: KHSO4, benzene-1,2-diol, picric acid / 220 °C
2: (i) NaBH4, BF3-Et2O, (EtOCH2CH2)2O, (ii) aq. NaOH, aq. H2O2
View Scheme
参考文献
DePuy,C.H. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 2746 - 2750
