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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
2,6-二溴碘苯
合成路线
（共 18 条）
108-36-1
1,3-二溴苯
→
反应条件
19821-80-8
2,6-二溴碘苯
反应条件
1: With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane T=-75°C; 2 h; 2: With iodine in tetrahydrofuran; hexane T=-75°C;
参考文献
Leroux, Frederic R.; Bonnafoux, Laurence; Heiss, Christophe; Colobert, Francoise; Lanfranchi, Don Antoine
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2705 - 2713
608-30-0
2,6-二溴苯胺
→
反应条件
19821-80-8
2,6-二溴碘苯
反应条件
1: With hydrogenchloride in water T=0 - 5°C; Sandmeyer reaction; Inert atmosphere; 2: With potassium iodide in dichloromethane; water T=25°C; Sandmeyer reaction; Inert atmosphereCooling with ice;
参考文献
Mao, Guoliang; Orita, Akihiro; Matsuo, Daisuke; Hirate, Takayoshi; Iwanaga, Tetsuo; Toyota, Shinji; Otera, Junzo
Tetrahedron Letters, 2009 , vol. 50, # 24 p. 2860 - 2864
401631-86-5
→
反应条件
108-36-1
1,3-二溴苯
+
19821-80-8
2,6-二溴碘苯
反应条件
tetrafluoroboric acid; hydrogen iodide in acetonitrile T=60°C; 24 h;
参考文献
Barbero; Degani; Diulgheroff; Dughera; Fochi
Synthesis, 2001 , # 14 p. 2180 - 2190
19821-80-8
2,6-二溴碘苯
+
2633-66-1
2,4,6-三甲基苯溴化镁
→
反应条件
103068-13-9
反应条件
in tetrahydrofuran 3 h; Ambient temperature;
参考文献
Du, Chi-Jen Frank; Hart, Harold; Ng, Kwok-Keung Daniel
Journal of Organic Chemistry, 1986 , vol. 51, # 16 p. 3162 - 3165
19821-80-8
2,6-二溴碘苯
+
98-80-6
苯硼酸
→
反应条件
59080-32-9
2,6-二溴联苯
反应条件
1: 1,3-dibromo-2-iodo-benzene With PEPPSI-IPr catalyst; potassium carbonate in 1,4-dioxane T=20°C; Suzuki-Miyaura coupling; 1 h; Inert atmosphere; 2: 3,4,5-trimethoxyphenylboronic acid in 1,4-dioxane Suzuki-Miyaura coupling; 36 h; Inert atmosphereReflux;
参考文献
Synthesis, , vol. 44, # 9 p. 1405 - 1409
19821-80-8
2,6-二溴碘苯
→
反应条件
19230-27-4
1,3-二溴-2-氯苯
反应条件
n-butyllithium; copper dichloride 1.) ether, hexane, -78 deg C, 2 h, 2.) ether, hexane, from -78 deg C to RT, 12 h; Multistep reaction. Yields of byproduct given;
参考文献
Journal of the American Chemical Society, , vol. 118, # 31 p. 7272 - 7279
104-92-7
4-溴苯甲醚
+
19821-80-8
2,6-二溴碘苯
→
反应条件
328249-41-8
反应条件
1: 1-bromo-4-methoxy-benzene With magnesium; ethylene dibromide in tetrahydrofuran 2 h; Heating; 2: 1,3-dibromo-2-iodo-benzene in tetrahydrofuran T=20°C; 3 h;
参考文献
Wegner, Gerald L.; Berger, Raphael J. F.; Schier, Annette; Schmidbaur, Hubert
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2000 , vol. 55, # 11 p. 995 - 999
19821-80-8
2,6-二溴碘苯
→
反应条件
92-06-8
间三联苯
反应条件
in tetrahydrofuran 3 h; Ambient temperature;
参考文献
Du, Chi-Jen Frank; Hart, Harold; Ng, Kwok-Keung Daniel
Journal of Organic Chemistry, 1986 , vol. 51, # 16 p. 3162 - 3165
19821-80-8
2,6-二溴碘苯
→
反应条件
13345-26-1
8-羟基苯并[a]芘
反应条件
1: tetrakis(triphenylphosphine) palladium(0); potassium fluoride / 1,4-dioxane / Reflux 2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine 3: methanol; potassium carbonate / tetrahydrofuran 4: platinum (II) chloride 5: boron tribromide View Scheme
参考文献
Wu, Anhui; Xu, Daiwang; Lu, Ding; Penning, Trevor M.; Blair, Ian A.; Harvey, Ronald G.
Tetrahedron, 2012 , vol. 68, # 35 p. 7217 - 7233
19821-80-8
2,6-二溴碘苯
→
反应条件
17573-21-6
9-羟基苯并(a)芘
反应条件
1: tetrakis(triphenylphosphine) palladium(0); potassium fluoride / 1,4-dioxane / Reflux 2: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine 3: methanol; potassium carbonate / tetrahydrofuran 4: platinum (II) chloride 5: boron tribromide View Scheme
参考文献
Wu, Anhui; Xu, Daiwang; Lu, Ding; Penning, Trevor M.; Blair, Ian A.; Harvey, Ronald G.
Tetrahedron, 2012 , vol. 68, # 35 p. 7217 - 7233
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