2,4-二甲基-1-戊烯-3-醇合成路线 （共 12 条）
反应条件
1: isopropenyl bromide With magnesium in tetrahydrofuran 0.5 h; RefluxInert atmosphere; 2: isobutyraldehyde in tetrahydrofuran T=0 - 20°C; Inert atmosphere;
参考文献
Schmidt, Yvonne; Breit, Bernhard
Chemistry - A European Journal, 2011 , vol. 17, # 42 p. 11780 - 11788
反应条件
in tetrahydrofuran 4 h;
参考文献
Bassetti, Mauro; D'Annibale, Andrea; Fanfoni, Alessia; Minissi, Franco
Organic Letters, 2005 , vol. 7, # 9 p. 1805 - 1808
参考文献
Massachusetts Institute of Technology
Patent: US6346652 B1, 2002 ;
Location in patent: Page column 29-30 ;
反应条件
1: O2 / methanol / 9.4 h / 27 °C / Irradiation; methylene blue 2: sodium borohydride / methanol View Scheme
参考文献
Umnowa
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1910 , vol. 42, p. 1533
Chem. Zentralbl., 1911 , vol. 82, # I p. 1279
反应条件
potassium carbonate T=80 - 85°C;
参考文献
Umnowa
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1910 , vol. 42, p. 1533
Chem. Zentralbl., 1911 , vol. 82, # I p. 1279
反应条件
sodium tetrahydroborate in methanol
参考文献
Brill, William F.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , # 4 p. 621 - 628
反应条件
1: potassium pyrosulphate / ethanol / Heating 2: O2 / methanol / 9.4 h / 27 °C / Irradiation; methylene blue 3: sodium borohydride / methanol View Scheme
参考文献
Brill, William F.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , # 4 p. 621 - 628
反应条件
(i) Mg, (ii) /BRN= 1209258/; Multistep reaction;
参考文献
Faulkner; Petersen
Journal of the American Chemical Society, 1973 , vol. 95, # 2 p. 553 - 563
参考文献
Ohmura, Toshimichi; Takasaki, Yuta; Furukawa, Hideki; Suginome, Michinori
Angewandte Chemie, International Edition, 2009 , vol. 48, # 13 p. 2372 - 2375
参考文献
Faulkner,D.J.; Petersen,M.R.
Tetrahedron Letters, 1969 , p. 3243 - 3246
