tris-(dibenzylideneacetone)dipalladium(0); (1,2,3,4,5-pentaphenylferrocen-1'-yl)-di-tert-butylphosphine in toluene T=20°C; 1 h;

1: bromobenzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; Negishi coupling reaction; 0.166667 h; Inert atmosphere; 2: With zinc(II) chloride in tetrahydrofuran; hexane T=-78 - 20°C; Negishi coupling reaction; Inert atmosphere; 3: 2-isopropylphenyl iodide With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran; hexane T=60°C; Negishi coupling reaction; 2 h; Inert atmosphere;

zeolite ZSM-12L T=250°C; P=6000.6 Torr; 4 h; Autoclave; Catalytic behavior; Reagent/catalystTemperature;

potassium acetate; isopentyl nitrite in benzene T=80°C; 10 h;

potassium acetate; isopentyl nitrite in benzene T=80°C; 10 h;

iodine 1.) THF, RT, 2.) a) -78 deg C, 3 h, b) RT, 3 h; Yield given. Multistep reaction. Yields of byproduct given;

trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); trifluoroacetic acid T=100°C; 24 h; Overall yield = 44 percent; Overall yield = 21.7 mg;

T=75°C;

Product distribution;

totally tritiated phenyl cation, gas and liquid phases at r.t., solid phase at temp. of liquid N2; Product distributionRate constant;