aluminium trichloride; isopropyl-benzene; benzene T=34.9°C; 7 h; var. temp., time, ΔrHm0, ΔrSm0; Thermodynamic dataEquilibrium constant;

tetrabutyl ammonium fluoride in water; toluene T=100°C; Hiyama Coupling; 20 h;

potassium carbonate; PdCl2[diisopropyl(o-isopropylphenyl)phosphane]2 in N,N-dimethyl-formamide T=150°C; Suzuki-Miyaura coupling reaction; 0.5 h; microwave irradiation;

1: 1-Bromo-2-isopropyl-benzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; Negishi coupling reaction; 0.166667 h; Inert atmosphere; 2: With zinc(II) chloride in tetrahydrofuran; hexane T=-78 - 20°C; Negishi coupling reaction; Inert atmosphere; 3: iodobenzene With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran; hexane T=60°C; Negishi coupling reaction; 2 h; Inert atmosphere;

ethanol; copper oxide-chromium oxide T=225°C; P=62518.2 Torr; Hydrogenation;

tris(dibenzylideneacetone)dipalladium(0) chloroform complex; cesium fluoride; 3-tert-butyl-5-methyl-1-(2-(diphenylphosphino)phenyl)-1H-pyrazole in toluene T=60°C; Stille coupling; 10 h; Inert atmosphere;

ethanol; nickel T=100°C; P=73550.8 Torr; Hydrogenation;

CPhos; palladium diacetate in tetrahydrofuran T=0 - 20°C; Negishi coupling reaction; Inert atmosphere;

tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tetrabutyl ammonium fluoride; 3-tert-butyl-5-methyl-1-(2-(diphenylphosphino)phenyl)-1H-pyrazole in 1,4-dioxane T=55°C; Hiyama coupling; 10 h; Inert atmosphere;

silica-alumina T=300°C; P=7500.75 Torr; Autoclave; Reagent/catalystTime;