hydrogenchloride; NaH; AlCl3 in N,N-dimethyl-formamide

potassium phosphate; [RhCl(η2:η2-cycloocta-1,5-diene)]2; bis(η3-allyl-μ-chloropalladium(II)); 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in methanol; 1,1-dimethylpropan-1-ol T=20 - 110°C; 16.08 h; Inert atmosphereSealed tube;

aluminum chloride in 1,2-dichloro-ethane

sodium azide; trichloroacetic acid T=60 - 65°C; Schmidt rearrangement; 16 h;

aluminium trichloride Verschmelzen;

aluminium trichloride T=140°C; 4 h; other methyl-substituted β-chloropropionanilides; var. time, var. temperature; Product distribution;

Schmelzen;