茚并(1,2,3-cd)芘合成路线 （共 31 条）
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene; bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=140°C; 11 h; Inert atmosphere;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: EP2316816 A1, 2011 ;
Location in patent: Page/Page column 23 ;
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine; tris(dibenzylideneacetone)dipalladium (0) in N,N-dimethyl-formamide T=155°C; 48 h;
参考文献
Wegner, Hermann A.; Reisch, Helge; Rauch, Karsten; Demeter, Attila; Zachariasse, Klaas A.; De Meijere, Armin; Scott, Lawrence T.
Journal of Organic Chemistry, 2006 , vol. 71, # 24 p. 9080 - 9087
反应条件
2: 4 N HCl / tetrahydrofuran / 2 h / Heating 3: 2,6-lutidine / CH2Cl2 / 1 h / -30 °C 4: 91 percent / LiCl, DBU / Pd(PPh3)2Cl2 / dimethylformamide / 6 h / 135 - 140 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 33, # 13 p. 1663 - 1678
反应条件
2: 4 N HCl / tetrahydrofuran / 2 h / Heating 3: 2,6-lutidine / CH2Cl2 / 1 h / -30 °C 4: 91 percent / LiCl, DBU / Pd(PPh3)2Cl2 / dimethylformamide / 6 h / 135 - 140 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 33, # 13 p. 1663 - 1678
反应条件
1: 4 N HCl / tetrahydrofuran / 2 h / Heating 2: 2,6-lutidine / CH2Cl2 / 1 h / -30 °C 3: 91 percent / LiCl, DBU / Pd(PPh3)2Cl2 / dimethylformamide / 6 h / 135 - 140 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 33, # 13 p. 1663 - 1678
反应条件
1: diisopropylethylamine / CH2Cl2 / 0 °C 3: 4 N HCl / tetrahydrofuran / 2 h / Heating 4: 2,6-lutidine / CH2Cl2 / 1 h / -30 °C 5: 91 percent / LiCl, DBU / Pd(PPh3)2Cl2 / dimethylformamide / 6 h / 135 - 140 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 33, # 13 p. 1663 - 1678
反应条件
1: 1.) n-butyllithium / 1.) hexane, ether, 2 h, 2.) ether, overnight 2: 68 percent / pyridinium dichromate / dimethylformamide / Ambient temperature 3: 1.) polyphosphoric acid (PPA), 2.) 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / 1.) 110 deg C, 2 h, 2.) benzene, reflux, 30 min View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 26 p. 5668 - 5678
反应条件
1: 71 percent / pyridinium dichromate / dimethylformamide / Ambient temperature 2: 1.) polyphosphoric acid (PPA), 2.) 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / 1.) 110 deg C, 2 h, 2.) benzene, reflux, 30 min View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 26 p. 5668 - 5678
反应条件
air T=840°C; P=19501.6 Torr; Formation of xenobioticshigh pressure combustion; Further byproducts given. Title compound not separated from byproducts;
参考文献
Chemosphere, , vol. 42, # 5-7 p. 681 - 690
反应条件
1: 68 percent / pyridinium dichromate / dimethylformamide / Ambient temperature 2: 1.) polyphosphoric acid (PPA), 2.) 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / 1.) 110 deg C, 2 h, 2.) benzene, reflux, 30 min View Scheme
参考文献
Journal of Organic Chemistry, , vol. 52, # 26 p. 5668 - 5678
