LiCl in methanol Electrochem. Process; anodic oxidation of W in MeOH in the presence of LiCl (110 V, 12 h); evapn. to dryness (vac.), extn. (hexane), drying (vac.); mixture of the 2 compds.;

methanol; Na in methanol; diethyl ether byproducts: NaCl; a soln. of WOCl4 in abs. ether added dropwise to a cooled (0°C) soln. of Na in abs. methanol with stirring, NaCl removed, further methanol added, boiled for 30 min; centrifugated, cooled to -20°C, solvent removed in vacuo; elem. anal.;

(C4H9)4NBr; methanol in methanol Electrolysis; for 8 h; anode(tungsten), cathode(platinum); isolated(hexane); crystallized; chem. anal., X-ray, IR, mass spectr.;

in methanol Electrochem. Process; anodic oxidn. of W in refluxing methanol with LiCl as electrolyte at total 50 V, 150 mA (as in: Seisenbaeva, G. A.; Werndrup, P.; Kloo, L.; Kessler, V. G. Inorg. Chem. 2001, 40, 3815 and Kessler, V. G. etal., J. Chem. Soc., Dalton Trans. 1998, 21); recrystn. (hexane);