1: phenyl-magnesium bromide With ZnI2(tmeda) in tetrahydrofuran 2: 2-adamantyl 4-methybenzenesulfonate With anhydrous iron chloride in tetrahydrofuran T=0 - 60°C;
sulfuric acid T=20°C; 1.5 h; methanesulfonic acid was used as well (instead of H2SO4), at 80 deg C;
参考文献
Isaev, S. D.; Zhalnina, G. G.; Murzinova, Z. N.; Lastovenko, S. I.; Yurchenko, A. G.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, p. 126 - 131
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 1 p. 142 - 148
in tetrahydrofuran; pentane T=-110°C; Dehalogenation; alkylation; cycloaddition; 0.416667 h; Further byproducts given;
参考文献
Okazaki, Takao; Tokunaga, Kazuhiko; Kitagawa, Toshikazu; Takeuchi, Ken'ichi
Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 3 p. 549 - 561
