2,2'-联(双环[2.2.1]庚烷)合成路线 （共 11 条）
反应条件
in xylene Irradiation;
参考文献
Kopp, Paul J.; Adkins, Rick L.
Journal of the American Chemical Society, 1991 , vol. 113, # 7 p. 2709 - 2717
反应条件
ammonium hydroxide in tert-butyl alcohol T=10°C; 3 h; Irradiation; Further byproducts given;
参考文献
Kopp, Paul J.; Adkins, Rick L.
Journal of the American Chemical Society, 1991 , vol. 113, # 7 p. 2709 - 2717
反应条件
1: 1.) Br2, PCl3, 2.) Bu3SnH / 2.) 35 deg C, overnight 2: 18 percent Chromat. / NH4OH / 2-methyl-propan-2-ol / 6 h / 10 °C / Irradiation 3: 85 percent / 48percent HBr / 9 h / 59 °C 4: 8 percent Chromat. / NH4OH / methanol / 6 h / 10 °C / Irradiation View Scheme
参考文献
Kopp, Paul J.; Adkins, Rick L.
Journal of the American Chemical Society, 1991 , vol. 113, # 7 p. 2709 - 2717
反应条件
1: 41 percent Chromat. / NH4OH / 2-methyl-propan-2-ol / 4 h / 10 °C / Irradiation 2: 1.) BH3, 2.) Br2, NaOMe / 1.) a) THF, 0 deg C, 30 min, b) 25 deg C, 30 min, 2.) THF, MeOH, 20-25 deg C 3: 4 percent Chromat. / NH4OH / 2-methyl-propan-2-ol / 6 h / 10 °C / Irradiation View Scheme
参考文献
Kopp, Paul J.; Adkins, Rick L.
Journal of the American Chemical Society, 1991 , vol. 113, # 7 p. 2709 - 2717
反应条件
1: 36 percent Chromat. / NH4OH / methanol / 1.5 h / 10 °C / Irradiation 2: 1.) BH3, 2.) Br2, NaOMe / 1.) a) THF, 0 deg C, 30 min, b) 25 deg C, 30 min, 2.) THF, MeOH, 20-25 deg C 3: 4 percent Chromat. / NH4OH / 2-methyl-propan-2-ol / 6 h / 10 °C / Irradiation View Scheme
参考文献
Kopp, Paul J.; Adkins, Rick L.
Journal of the American Chemical Society, 1991 , vol. 113, # 7 p. 2709 - 2717
反应条件
1: 27 percent Chromat. / NH4OH / methanol / 6 h / 10 °C / Irradiation 2: 1.) BH3, 2.) Br2, NaOMe / 1.) a) THF, 0 deg C, 30 min, b) 25 deg C, 30 min, 2.) THF, MeOH, 20-25 deg C 3: 4 percent Chromat. / NH4OH / 2-methyl-propan-2-ol / 6 h / 10 °C / Irradiation View Scheme
参考文献
Kopp, Paul J.; Adkins, Rick L.
Journal of the American Chemical Society, 1991 , vol. 113, # 7 p. 2709 - 2717
反应条件
hydrogen; platinum on silica T=15°C; passing over the catalyst in H2;
参考文献
Laverty, D. Theodore; Rooney, John J.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1983 , vol. 79, p. 869 - 878
反应条件
mono(acetonitrile)tris(triphenylphosphine)palladium(II) bis(tetrafluoroborate); hydrogen in nitromethane 1 h;
参考文献
Blank, Frederik; Scherer, Harald; Janiak, Christoph
Journal of Molecular Catalysis A: Chemical, 2010 , vol. 330, # 1-2 p. 3958 - 3968
反应条件
N(Et)4ClO4 in N,N-dimethyl-formamide electrolytic reduction; Electrolysis; Product distribution; Further Variations:electron per mol.;
参考文献
Prigent, Sylvie; Cauliez, Pascal; Simonet, Jacques; Peters, Dennis G.
Acta Chemica Scandinavica, 1999 , vol. 53, # 10 p. 892 - 900
反应条件
T=116°C; 3.66667 h; Product distribution; Further Variations:reaction time;
参考文献
Bencze; Biro; Szabo-Ravasz; Mihichuk
Canadian Journal of Chemistry, 2004 , vol. 82, # 4 p. 499 - 503
