[2,2-二(三甲基硅烷基)乙烯基](三甲基)硅烷合成路线 （共 15 条）
反应条件
1: 1.) Mg; 2.) tribromophosphane / 1.) THF; 2.) THF, ether, 2 h, room temp.
2: 1.) 1.6N n-BuLi / 1.) THF, ether, pentane, hexane, 3 h, -100 deg C; 2.) THF, ether, pentane, hexane, -100 deg C to room temp.
3: 160 °C
View Scheme
参考文献
Niecke, Edgar; Leuer, Martina; Nieger, Martin
Chemische Berichte, 1989 , vol. 122, p. 453 - 462
参考文献
Bock,H.; Seidl,H.
Journal of Organometallic Chemistry, 1968 , vol. 13, p. 87 - 102
反应条件
(i) HSiCl3, (ii) /BRN= 3587200/; Multistep reaction;
参考文献
Quass,L.C. et al.
Journal of Organometallic Chemistry, 1970 , vol. 21, p. 65 - 73
反应条件
tris(1,3-divinyl-1,1,3,3-tetramethyldisiloxane)-bis-platinum(0)
T=130°C; 7 h; other trisilylethenes; reaction with addition of HexMe2SiH; Product distribution;
参考文献
Suzuki, Toshio; Lo, Peter Y.
Journal of Organometallic Chemistry, 1991 , vol. 402, # 1 p. 27 - 33
反应条件
bis(1,3-divinyl-1,1,3,3,-tetramethyldisiloxane)Pt(0)
T=130°C; 6 h; var. disilylethynes, and hydrosilanes, other times; Product distributionMechanism;
参考文献
Suzuki, Toshio; Lo, Peter Y.
Journal of Organometallic Chemistry, 1990 , vol. 391, # 1 p. 19 - 25
