2,5-二甲基-3-己酮合成路线 (共 29 条)
反应条件
1: bromine / 0 °C / und Behandeln des Reaktionsprodukts mit Natriummethylat in Aether 2: aqueous hydriodic acid View Scheme
参考文献
Sacks; Aston
Journal of the American Chemical Society, 1951 , vol. 73, p. 3902,3904
反应条件
sodium dichromate; sulfuric acid in diethyl ether
2.5 h; Ambient temperature;
参考文献
Kuttenberger, Margit; Frieser, Markus; Hofweber, Martin; Mannschreck, Albrecht
Tetrahedron Asymmetry, 1998 , vol. 9, # 20 p. 3629 - 3645
反应条件
lithium tetrachloromanganate(II) in tetrahydrofuran; diethyl ether
T=0 - 20°C; 1.5 h;
参考文献
Kraft, Philip; Popaj, Kasim
Tetrahedron, 2006 , vol. 62, # 52 p. 12211 - 12219
反应条件
aluminium trichloride
T=70°C; P=110326 Torr;
参考文献
Balaban; Nenitzescu
Justus Liebigs Annalen der Chemie, 1959 , vol. 625, p. 66,72
Full Text Show Details
Hopff
Ang.Ch.<A>, 1948 , vol. 60, p. 218
反应条件
T=70°C; P=73550.8 Torr; Hydrogenation;
参考文献
Universal Oil Prod.Co.
Patent: US2346701 , 1941 ;
Full Text Show Details
Pines; Ipatieff
Journal of the American Chemical Society, 1947 , vol. 69, p. 1338
反应条件
1: (i) TsOH, Ac2O, (ii) (anodic oxidation), /BRN= 1098229/, <Et4N>OTs
2: diethyl ether
3: aq. H2SO4
View Scheme
参考文献
Shono,T. et al.
Chemistry Letters, 1976 , p. 1319 - 1322
参考文献
Percival et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 3731,3733
Full Text Show Details
Herzog; Buchman
Journal of Organic Chemistry, 1951 , vol. 16, p. 99,101
反应条件
1: 90 percent / (Me3Si)2NH / CH2Cl2 / Ambient temperature
2: 43 percent Chromat. / Me2PhSiLi / tetrahydrofuran / 20 h / 10 °C
View Scheme
参考文献
Fleming, Ian; Roberts, Richard S.; Smith, Stephen C.
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 7 p. 1215 - 1228
参考文献
Kanao; Yaguchi
Yakugaku Zasshi, 1928 , vol. 48, p. 71
Chem. Zentralbl., 1928 , vol. 99, # II p. 52
反应条件
hydrogenchloride; acetic acid; zinc
48 h; Ambient temperature;
参考文献
Floris, Barbara; Luchetti, Luciana; Rosnati, Vittorio
Tetrahedron, 1993 , vol. 49, # 20 p. 4409 - 4418