2,4-二甲基-3-己酮合成路线 （共 17 条）
反应条件
1: SOCl2
2: 60 percent / tetrahydrofuran / 1.) -30 deg C, 1 h, 2.) -30 deg C to room temp.
View Scheme
参考文献
Dubois, Jacques-Emile; Lion, Claude; Arouisse, Abdelmajid
Bulletin des Societes Chimiques Belges, 1984 , vol. 93, # 12 p. 1083 - 1088
参考文献
Whitmore et al.
Journal of the American Chemical Society, 1950 , vol. 72, p. 53
反应条件
1: 40 percent / diethyl ether; various solvent(s) / 0.5 h / -78 °C
2: 82 percent / diethyl ether; various solvent(s) / 0.5 h / -78 °C
View Scheme
参考文献
Barbee, Thomas R.; Albizati, Kim F.
Journal of Organic Chemistry, 1991 , vol. 56, # 24 p. 6764 - 6773
反应条件
1: 10 percent / diethyl ether; various solvent(s) / 0.5 h / -78 °C
2: 82 percent / diethyl ether; various solvent(s) / 0.5 h / -78 °C
View Scheme
参考文献
Barbee, Thomas R.; Albizati, Kim F.
Journal of Organic Chemistry, 1991 , vol. 56, # 24 p. 6764 - 6773
反应条件
in N,N,N',N',N'',N''-hexamethylphosphoric triamide
参考文献
Huet,F. et al.
Tetrahedron, 1973 , vol. 29, p. 479 - 485
反应条件
Cu-Zn-Mg-Al based catalyst; hydrogen reduced
T=249.84°C; Product distribution / selectivity;
参考文献
Yuan Ze University
Patent: US7314960 B1, 2008 ;
Location in patent: Page/Page column 4-8 ;
反应条件
(i) THF, (ii) H2O, oxalic acid; Multistep reaction;
参考文献
Lion,C.; Dubois,J.E.
Tetrahedron, 1973 , vol. 29, p. 3417 - 3423
