NaCl in pentane A Schlenck flask is charged with activated Li and NaCl in abs. pentane, Hg(GeMe3)2 is added dropwise over 2 h, and left for 32 h at room temp.; decantation and concn. yields a 0.2 M soln. of product in pentane;
参考文献
Schumann, Herbert; Nickel, Siegbert; Loebel, Joerg; Pickardt, Joachim
Organometallics, 1988 , vol. 7, p. 2004 - 2009
in ethylene glycol dimethyl ether; pentane LiGeMe3 in pentane is dropped slowly to a soln. of Sm complex in DME; reaction for 4 h at room temp.; decantation, concn., cooling to -78°C; pptn. of bis(tris(cyclopentadienyl)samarium complex the next day, (Cp2SmCl)2 crystallizes from the decanted soln.; elem. anal.;
参考文献
Schumann, Herbert; Nickel, Siegbert; Loebel, Joerg; Pickardt, Joachim
Organometallics, 1988 , vol. 7, p. 2004 - 2009
→
反应条件
in pentane
参考文献
Schumann, H.; Albrecht, I.; Gallagher, M.; Hahn, E.; Janiak, C.; et al.
Polyhedron, 1988 , vol. 7, p. 2307 - 2316
