1-乙炔-2,4-二硝基苯合成路线 （共 4 条）
反应条件
trichlorophosphate in 1,4-dioxane T=80°C; 4 h; Yields of byproduct given;
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
1: 65 percent / triethylamine / benzene / 2 h / 40 °C / 20 degC, overnight 2: 39 percent / POCl3 / dioxane / 4 h / 80 °C View Scheme
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
1: SOCl2 / benzene / 1.5 h / Heating 2: 65 percent / triethylamine / benzene / 2 h / 40 °C / 20 degC, overnight 3: 39 percent / POCl3 / dioxane / 4 h / 80 °C View Scheme
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
methanol; sodium hydroxide T=0 - 25°C; Kinetics;
参考文献
Marchese,G. et al.
Tetrahedron, 1968 , vol. 24, p. 663 - 674
