in neat (no solvent) addn. of SbF3 to a boiling soln. of Br2 free SiBr4 under stirring;; distillation;;
参考文献
Schumb, W. C.; Anderson, H. C.
Journal of the American Chemical Society, 1936 , vol. 58, p. 994 - 996
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Gmelin Handbook: Si: MVol.B, 271, page 730 - 732
in neat (no solvent) The halogen was co-condensed in a flask at -196°C with the mixt. of SiF4 and SiF2 emerging out of the reactor tube; further products;; warmed to room temp.; the volatile products were sepd. and detected by NMR and MS;;
参考文献
Suresh, Bettadapura S.; Thompson, James Charlton
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1987 , p. 1123 - 1126
Schumb, W. C.; Anderson, H. H.
Journal of the American Chemical Society, 1937 , vol. 59, p. 651 - 653
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Gmelin Handbook: Si: MVol.B, 272, page 732 - 735
in neat (no solvent) byproducts: Br2; on slight warming;;
参考文献
Schumb, W. C.; Anderson, H. H.
Journal of the American Chemical Society, 1937 , vol. 59, p. 651 - 653
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.B, 272, page 732 - 735
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, three equiv. of tinhydride, reactn. time 0.5 h; not isolated; IR spectroscopy (identified 60percent SiH4, 20percent SiF3H and 20percent SiF2H2 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
