1,1-二甲基-2-丙烯基苯合成路线 （共 31 条）
反应条件
di-tert-butyl peroxide T=135 - 140°C; 24 h;
参考文献
Abramovici,M.; Pines,H.
Journal of Organic Chemistry, 1969 , vol. 34, p. 266 - 270
反应条件
hydrogen; triphenylphosphine; lt;closo-3,3-(PPh3)2-3-H-3,1,2-RhC2B9H11gt; in tetrahydrofuran T=40.8°C; further rhodacarborane catalyst; also in the presence of bases, D2O, radical scavengers; labelled experiments; Rate constantMechanism;
参考文献
Behnken, Paul E.; Belmont, James A.; Busby, David C.; Delaney, Mark S.; King, Roswell E.; et al.
Journal of the American Chemical Society, 1984 , vol. 106, p. 3011 - 3025
反应条件
hydrogen bromide T=50°C; Irradiation.UV-Licht;
参考文献
Breederveld; Kooyman
Recueil des Travaux Chimiques des Pays-Bas, 1957 , vol. 76, p. 297,310
反应条件
silver trifluoromethanesulfonate; triphenylphosphine; allyl nickel bromide dimer in dichloromethane
T=0°C; 2 h;
参考文献
RajanBabu; Nomura, Nobuyoshi; Jin, Jian; Nandi, Malay; Park, Haengsoon; Sun, Xiufeng
Journal of Organic Chemistry, 2003 , vol. 68, # 22 p. 8431 - 8446
反应条件
BF3*AcOH in dichloromethane
T=0°C; 0.25 h;
参考文献
Fleming, Ian
Bulletin de la Societe Chimique de France, 1981 , vol. 2, # 1-2 p. 7 - 13
反应条件
BF3·2HOAc in dichloromethane
T=0°C; 0.25 h;
参考文献
Fleming, Ian; Patel, Shailesh K.; Urch, Christopher J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 115 - 124
反应条件
n-butyllithium in diethyl ether; hexane
1.) RT, 4 h; 2.) reflux, 12 h;
参考文献
Behnken, Paul E.; Belmont, James A.; Busby, David C.; Delaney, Mark S.; King, Roswell E.; et al.
Journal of the American Chemical Society, 1984 , vol. 106, p. 3011 - 3025
反应条件
T=-196.1°C; P=5E-05 Torr;
参考文献
Armstrong, Brian M.
Journal of the American Chemical Society, 1998 , vol. 120, # 24 p. 6007 - 6011
反应条件
1: 52 percent / 1.) NaH / tetrahydrofuran / 2 h / Heating
2: 72 percent / nBuLi / hexane; diethyl ether / 1.) RT, 4 h; 2.) reflux, 12 h
View Scheme
参考文献
Behnken, Paul E.; Belmont, James A.; Busby, David C.; Delaney, Mark S.; King, Roswell E.; et al.
Journal of the American Chemical Society, 1984 , vol. 106, p. 3011 - 3025
反应条件
in tetrahydrofuran
24 h;
参考文献
Matsushita,H.; Negishi,E.I.
Journal of the American Chemical Society, 1981 , vol. 103, p. 2882
