2,3,4,5,6-五氯联苯合成路线 （共 11 条）
反应条件
copper(l) iodide; 1,10-phenanthroline; lithium tert-butylate in N,N-dimethyl-formamide T=120°C; 12 h; Inert atmosphere;
参考文献
Do, Hien-Quang; Khan, Rana M. Kashif; Daugulis, Olafs
Journal of the American Chemical Society, 2008 , vol. 130, # 45 p. 15185 - 15192
反应条件
potassium methanolate; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride; bis(dibenzylideneacetone)-palladium(0) in methanol; toluene T=95°C; Suzuki coupling;
参考文献
Russian Chemical Bulletin, , vol. 56, # 7 p. 1467 - 1469
反应条件
potassium phosphate; 18-crown-6 ether; 1,3-phenylene-bis-(1H)-tetrazole; palladium diacetate in N,N-dimethyl-formamide T=95°C; Suzuki cross-coupling; 7 h; Title compound not separated from byproducts;
参考文献
Russian Chemical Bulletin, , vol. 55, # 1 p. 118 - 122
反应条件
1: hexachloro-benzene With potassium phosphate; 18-crown-6 ether; 1,3-phenylene-bis-(1H)-tetrazole; palladium diacetate in N,N-dimethyl-formamide 0.166667 h; 2: 3,4,5-trimethoxyphenylboronic acid in N,N-dimethyl-formamide T=90°C; 7 h;
参考文献
Russian Chemical Bulletin, , vol. 54, # 4 p. 970 - 974
反应条件
1: bromobenzene With n-butyllithium in tetrahydrofuran; hexane 0.333333 h; cooling; 2: With zinc(II) chloride in tetrahydrofuran; hexane T=20°C; 0.333333 h; 3: hexachloro-benzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane Negishi coupling; 24 h; Heating;
参考文献
Russian Chemical Bulletin, , vol. 54, # 4 p. 970 - 974
参考文献
Bratt, Jack; Iddon, Brian; Mack, Arthur G.; Suschitzky, Hans; Taylor, Jack A.; Wakefield, Basil J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 648 - 656
反应条件
ethylmagnesium bromide in tetrahydrofuran Grignard reaction;
参考文献
Chemosphere, , vol. 31, # 2 p. 2687 - 2705
反应条件
copper in N,N-dimethyl-formamide Ulman reaction; Heating;
参考文献
Chemosphere, , vol. 31, # 2 p. 2687 - 2705
反应条件
titanium(III) citrate-reduced vitamin B12s in methanol; water T=20°C; Dehalogenation; pH=8.2; 1920 h; in the dark; Equilibrium constant;
参考文献
Woods, Sandra L.; Trobaugh, Darin J.; Carter, Kim J.
Environmental Science and Technology, 1999 , vol. 33, # 6 p. 857 - 863
反应条件
titanium(III) citrate-reduced vitamin B12s in methanol; water T=20°C; Dehalogenation; pH=8.2; 1920 h; in the dark; Equilibrium constant;
参考文献
Woods, Sandra L.; Trobaugh, Darin J.; Carter, Kim J.
Environmental Science and Technology, 1999 , vol. 33, # 6 p. 857 - 863
