1-(三甲基硅烷基乙炔基)环己醇合成路线 （共 16 条）
反应条件
1: trimethylsilylacetylene With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran; hexane T=-78°C; 2: cyclohexanone in tetrahydrofuran; hexane T=-78°C; Further stages.;
参考文献
Yoshida, Masahiro; Hayashi, Maiko; Shishido, Kozo
Organic Letters, 2007 , vol. 9, # 9 p. 1643 - 1646
反应条件
n-butyllithium in tetrahydrofuran; hexane T=0°C; 2 h;
参考文献
Carroll, Laurence; Pacheco, Ma. Carmen; Garcia, Ludivine; Gouverneur, Veronique
Chemical Communications, 2006 , # 39 p. 4113 - 4115
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
参考文献
Yoshimatsu, Mitsuhiro; Kuribayashi, Masako
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 11 p. 1256 - 1257
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
参考文献
Yoshimatsu, Mitsuhiro; Kuribayashi, Masako
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 11 p. 1256 - 1257
参考文献
Yarosh, O. G.; Zhilitskaya, L. V.; Albanov, A. I.; Burnashova, T. D.; Voronkov, M. G.
Russian Journal of General Chemistry, 1995 , vol. 65, # 4.1 p. 547 - 549
Zhurnal Obshchei Khimii, 1995 , vol. 65, # 4 p. 609 - 611
反应条件
methanol; ethanolamine 1) pentane, 25 deg C, 16 h, 2) ether, overnight; Yield given. Multistep reaction;
参考文献
Evans, Jonathan C.; Goralski, Christian T.; Hasha, Dennis L.
Journal of Organic Chemistry, 1992 , vol. 57, # 10 p. 2941 - 2943
反应条件
folgendes Umsetzen mit Brom-trimethyl-silan;
参考文献
Petrow et al.
Doklady Akademii Nauk SSSR, 1957 , vol. 115, p. 522,524
Doklady Chemistry, 112-117<1957>767
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
反应条件
1: LiAlH4 / tetrahydrofuran / Heating
2: Et3N / diethyl ether / -25 °C
3: 2.) AgNO3 / 1.) room temp. 2.) aq. acetonitrile
View Scheme
参考文献
Cutting, Ian; Parsons, Philip J.
Tetrahedron Letters, 1981 , vol. 22, # 21 p. 2021 - 2022
反应条件
(i) MeSO2Cl, Et3N, (ii) /BRN= 3587200/, LiCuBr2; Multistep reaction;
参考文献
Wenkert, Ernest; Leftin, Michael H.; Michelotti, Enrique L.
Journal of Organic Chemistry, 1985 , vol. 50, # 7 p. 1122 - 1124
