7-亚甲基双环[3.3.1]壬-3-酮合成路线 （共 44 条）
反应条件
3-chloro-benzenecarboperoxoic acid in dichloromethane 4 h; Ambient temperature; Yield given;
参考文献
Muraoka; Wang; Okumura; Nishiura; Tanabe; Momose
Synthetic Communications, 1996 , vol. 26, # 8 p. 1555 - 1562
反应条件
1: LiAlH4 / tetrahydrofuran / 1) reflux, 1 h; 2) rt, 4 h 2: 1.) p-toluenesulfonic acid chloride, pyridine, 2.) LiCl / 1) overnight; 2) 24 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 63, # 14 p. 4581 - 4586
反应条件
phosphorus pentachloride; phosphorus trichoride 4 h; Heating;
参考文献
Yurchenko, R. I.; LAvrova, E. E.; Luk'yanova, S. M.; Verpovskii, N. S.
J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 1 p. 242 - 243,212 - 213
反应条件
methanol; tetraethylammonium tetrafluoroborate in N,N-dimethyl-formamide
T=0°C; Electrolysis;
参考文献
Itoh; Kato; Unoura; Senda
Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 2 p. 339 - 345
反应条件
(i) Na, (ii) aq. HCl; Multistep reaction;
参考文献
Molle, Gerard; Bauer, Pierre
Journal of the American Chemical Society, 1982 , vol. 104, # 12 p. 3481 - 3487
反应条件
methylsulfinyl carbanion-DMSO
T=60°C; 17 h;
参考文献
Mink, Larry; Rettig, Michael F.; Wing, Richard M.
Journal of the American Chemical Society, 1991 , vol. 113, # 6 p. 2065 - 2071
反应条件
in tetrahydrofuran
T=190°C;
参考文献
Stetter,H.; Gaertner,J.
Chemische Berichte, 1966 , vol. 99, p. 925 - 929
反应条件
hydroxylamine hydrochloride in pyridine
T=20°C; 4 h;
参考文献
Shibuya, Masatoshi; Tomizawa, Masaki; Suzuki, Iwao; Iwabuchi, Yoshiharu
Journal of the American Chemical Society, 2006 , vol. 128, # 26 p. 8412 - 8413
反应条件
1.1: 100 percent / HONH2*HCl / pyridine / 4 h / 20 °C
2.1: MoO3; NaBH4 / methanol / 2 h / 0 °C
3.1: 159 mg / I2 / acetonitrile / 3 h / 20 °C
4.1: LiAlH4 / tetrahydrofuran / 0.5 h / 70 °C
5.1: Na2WO4*2H2O / H2O; methanol / 30 h / 20 °C
5.2: 777 mg / H2O2 / H2O; methanol / 3.5 h / 0 - 20 °C
View Scheme
参考文献
Shibuya, Masatoshi; Tomizawa, Masaki; Suzuki, Iwao; Iwabuchi, Yoshiharu
Journal of the American Chemical Society, 2006 , vol. 128, # 26 p. 8412 - 8413
反应条件
1: 1.) sodium cut, 2.) water / 1.) ether, 2.) reflux, 7 h
2: 77 percent / thionyl bromide / CH2Cl2 / 3 h / Heating
View Scheme
参考文献
Molle, Gerard; Bauer, Pierre
Journal of the American Chemical Society, 1982 , vol. 104, # 12 p. 3481 - 3487
