1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate in toluene T=85°C; 8 h;

dichloro(cycloocta-1,5-diene)palladium(II); N,N-dicyclohexylmethylamine; triethylamine; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; magnesium chloride; [(t-Bu)3PH]BF4 in 1,4-dioxane T=80°C; 18 h; Inert atmosphereGlovebox;

1,1'-bis-(diphenylphosphino)ferrocene; tris(dibenzylideneacetone)dipalladium (0); Ti-N complexes; sodium t-butanolate in toluene T=70°C; 1 h;

potassium acetate; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate in dimethyl sulfoxide T=60°C; 3 h;

1: 4-PhC6H4-OTf With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel (0); N,N-dicyclohexylmethylamine Heck Reaction; Sealed tubeGloveboxInert atmosphere; 2: 4-methoxy-1-vinyl-benzene With (SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium T=100°C; 20 h; GloveboxInert atmosphereSealed tube;

tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene in various solvent(s) T=60°C; 8 h;

1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium carbonate in N,N-dimethyl acetamide T=140°C; 24 h; Inert atmosphere;

[Pd(η3-1-Ph-allyl)(μ-Cl)]2; t-Bu Brett Phos; cesium fluoride in cyclohexane T=100°C; 12 h;

[Pd(η3-1-Ph-allyl)(μ-Cl)]2; t-Bu Brett Phos; cesium fluoride in toluene T=100°C; 12 h;

1: 1,1'-bis-(diphenylphosphino)ferrocene; [Ni0(1,5-cyclooctadiene)2]; N,N-dicyclohexylmethylamine / 1,4-dioxane / 20 h / 100 °C / Inert atmosphere 2: hydrogenchloride / 1,4-dioxane; water / 1 h / 20 °C / Inert atmosphere View Scheme