2,3,4,5,6-五氟溴化苄合成路线 （共 48 条）
反应条件
1: dimethylmono-chlorosilane With iodine; magnesium in diethyl ether T=35°C; 2: 2,3,4,5,6-pentafluoro-α-bromo-toluene in diethyl ether T=35°C; 2.25 h;
参考文献
Trost, Barry M.; Bertogg, Andreas
Organic Letters, 2009 , vol. 11, # 3 p. 511 - 513
参考文献
Chien, Chao-Jung; Charles, M. Judith; Sexton, Kenneth G.; Jeffries, Harvey E.
Environmental Science and Technology, 1998 , vol. 32, # 2 p. 299 - 309
反应条件
18-crown-6 ether; potassium carbonate in acetone
T=40 - 60°C; Esterification; 3 h;
参考文献
Chien, Chao-Jung; Charles, M. Judith; Sexton, Kenneth G.; Jeffries, Harvey E.
Environmental Science and Technology, 1998 , vol. 32, # 2 p. 299 - 309
参考文献
Birchall,J.M.; Haszeldine,R.N.
Journal of the Chemical Society, 1961 , p. 3719 - 3727
参考文献
Ehrhardt, Claudia; Fettkenhauer, Christian; Glenneberg, Jens; Muenchgesang, Wolfram; Leipner, Hartmut S.; Diestelhorst, Martin; Lemm, Sebastian; Beige, Horst; Ebbinghaus, Stefan G.
Journal of Materials Chemistry A, 2014 , vol. 2, # 7 p. 2266 - 2274
反应条件
potassium hydroxide in methanol
1 h; Heating;
参考文献
Trachsel, Daniel
Helvetica Chimica Acta, 2003 , vol. 86, # 7 p. 2610 - 2619
反应条件
1.1: 95 percent / KOH / methanol / 1 h / Heating
2.1: POCl3 / 15 - 60 °C
2.2: 45 percent / H2O / 0.5 h
View Scheme
参考文献
Trachsel, Daniel
Helvetica Chimica Acta, 2003 , vol. 86, # 7 p. 2610 - 2619
反应条件
silver fluoride
1.) diglyme, 2h, 35 deg C, 2.) 35-37 deg C, 3 d; Yield given. Multistep reaction;
参考文献
Chen, Li-Fo; Mohtasham, Javid; Gard, Gary L.
Journal of Fluorine Chemistry, 1990 , vol. 49, # 3 p. 331 - 347
反应条件
1: aq. ethanol
2: H2SO4
View Scheme
参考文献
Barbour,A.K. et al.
Journal of the Chemical Society, 1961 , p. 808 - 817
反应条件
pentacarbonyliron(0); tris-(dimethylamino)-phosphine in chlorobenzene
T=110°C; Zaitsev-Barbier reaction;
参考文献
Terent'Ev; Vasil'Eva; Ambartsumyan; Chakhovskaya; Mysova; Kochetkov
Russian Journal of Organic Chemistry, 2009 , vol. 45, # 8 p. 1181 - 1184
