4,4'-二氨基二环己基甲烷合成路线 （共 13 条）
反应条件
1: With lithium hydroxide; hydrogen in tetrahydrofuran T=190°C; P=44718.8 Torr; 0 - 0.1 h; 2: 4,4'-diaminodiphenylmethane With hydrogen T=185°C; P=42133 Torr; 2.66667 - 3.15 h; Product distribution / selectivity;
参考文献
Ding, Hao; Vedage, Gamini Ananda; Martine, William R.; Dholakia, Vipul P.
Patent: US2005/261525 A1, 2005 ;
Location in patent: Page/Page column 4 ;
反应条件
hydrogen; 5 ruthenium/lithium aluminate in tetrahydrofuran T=180°C; P=41372.9 Torr; 8 h; Product distribution / selectivity;
参考文献
Vedage, Gamini Ananda; Ding, Hao; Engel, Matthew J.; Lutz, Eugene George; Emig, Lenore Ann
Patent: US2007/66849 A1, 2007 ;
Location in patent: Page/Page column 7-8 ;
反应条件
hydrogen; 5 ruthenium/lithium aluminate in tetrahydrofuran T=180 - 190°C; P=41372.9 - 43958.7 Torr; 12 h; Product distribution / selectivity;
参考文献
EP1767520 A1, ;
Page/Page column 11 ;
反应条件
hydrogen; 5 wt. ruthenium on carbon in methanol T=160°C; P=30003 - 45004.5 Torr; 2.5 h; Industry scale; Product distribution / selectivity;
参考文献
EP2502900 A1, ;
Page/Page column 8 ;
反应条件
hydrogen; 5 Ru/Al2O3 in tetrahydrofuran T=83 - 105°C;
参考文献
WO2004/7425 A2, ;
Page 9-12 ;
反应条件
hydrogen; 5 Ru/Al2O3 in tetrahydrofuran T=90 - 110°C;
参考文献
WO2004/7425 A2, ;
Page 9-12 ;
反应条件
in 1-methyl-pyrrolidin-2-one; water
参考文献
Bayer Aktiengesellschaft
Patent: US4419520 A1, 1983 ;
反应条件
1: in butan-1-ol T=135°C; P=760.051 Torr; 8 h; 2: With butan-1-ol T=190 - 220°C; P=8250.83 - 10501.1 Torr; 10.5 h; 3: With tin(ll) chloride T=235 - 237°C; P=6.75068 - 7.50075 Torr; Product distribution / selectivity;
参考文献
DEGUSSA AG
Patent: US2005/250960 A1, 2005 ;
Location in patent: Page/Page column 7-8 ;
反应条件
T=360°C; P=300.03 Torr; Gas phase; Product distribution / selectivity;
参考文献
Ding, Jiansheng; Shang, Yong hua; Ma, Deqiang; Hao, Jingquan; Luo, Peicheng; Hu, Shuang
Patent: US2010/137634 A1, 2010 ;
Location in patent: Page/Page column 3 ;
反应条件
1: phenol / ferrous acetylacetonate / 50 °C / Industry scale 2: 240 h / 170 - 220 °C / 3.75 - 757.58 Torr View Scheme
参考文献
Asahi Kasei Chemicals Corporation
Patent: EP2322504 A1, 2011 ;
