顺式-1,2-环己二醇二乙酸酯合成路线 (共 65 条)
反应条件
water in hexane 168 h; enzyme-catalyzed hydrolysis with lipase Amano P30 (phosphate buffer, sodium chloride, pH 7.0, maintained with aq. NaOH);
参考文献
Caron, Gaetan; Kazlauskas, Romas J.
Journal of Organic Chemistry, 1991 , vol. 56, # 26 p. 7251 - 7256
反应条件
lipase enzyme from Pseudomonas sp in water T=20°C; 22 h; in 0.1M phosphate buffer (pH 7);
参考文献
Crout, David H. G.; Gaudet, Veronique S. B.; Laumen, Kurt; Schneider, Manfred P.
Journal of the Chemical Society, Chemical Communications, 1986 , # 10 p. 808 - 810
反应条件
lipase AK; water T=20°C; 24 h;
参考文献
Bodai, Viktoria; Orovecz, Oliver; Szakacs, Gyoergy; Novak, Lajos; Poppe, Laszlo
Tetrahedron Asymmetry, 2003 , vol. 14, # 17 p. 2605 - 2612
反应条件
D-glucose; water T=25°C; 3 h; Marchantia polymorpha;
参考文献
Gotoh, Shisei; Aoki, Masahiro; Iwaeda, Tomoko; Izumi, Shunsuke; Hirata, Toshifumi
Chemistry Letters, 1994 , # 8 p. 1519 - 1520
反应条件
water T=25°C; 168 h; porcine liver esterase, ammonium sulfate, phosphate buffer 7.0 (maintained with aq. NaOH), or with hexane or toluene, other enzymes (lipase from Pseudomonas cepacia and others), other reaction times, relative rates, enantioselectivity; Product distributionEquilibrium constantMechanism;
参考文献
Caron, Gaetan; Kazlauskas, Romas J.
Journal of Organic Chemistry, 1991 , vol. 56, # 26 p. 7251 - 7256