4,4,5-三甲基-2-环己烯-1-酮合成路线 （共 6 条）
反应条件
sulfuric acid 16 h; Heating;
参考文献
Flaugh, Michael E.; Crowell, Thomas A.; Farlow, Diane S.
Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5399 - 5400
反应条件
1: 1.) TiCl4 / 1.) CH2Cl2, -78 deg C, 5 min, 2.) CH2Cl2, -78 deg C, 20 min 2: 5percent ethanolic KOH / 1 h / Heating View Scheme
参考文献
Hagenbruch, Bernd; Huenig, Siegfried
Chemische Berichte, 1983 , vol. 116, # 12 p. 3884 - 3894
参考文献
Cook,K.L.; Waring,A.J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1973 , p. 529 - 537
反应条件
1: 95 percent / CuI / diethyl ether / 0.5 h / 0 °C 2: 70 percent / Br2 / acetic acid / 1) 2 h, 0 deg C, 2) 30 min, r.t. 3: 82 percent / CaCO3 / dimethylformamide / Heating View Scheme
参考文献
Cook,K.L.; Waring,A.J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1973 , p. 529 - 537
反应条件
1: H2 / PtO2
2: (i) Br2, (ii) CaCO3
View Scheme
参考文献
Cook,K.L.; Waring,A.J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1973 , p. 529 - 537
反应条件
1: (i) CuI, (ii) /BRN= 1816881/
2: (i) pyrrolidin-2-on tribromide, (ii) CaCO3
View Scheme
参考文献
Cook,K.L.; Waring,A.J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1973 , p. 529 - 537
