(S)-(+)-5-己烯-2-醇合成路线 （共 51 条）
反应条件
potassium tert-butylate; hydrogen; RuHCl(PPh2CH2CH2NH2)2 T=20°C; P=2280 Torr; 12 h;
参考文献
Rautenstrauch, Valentin; Churlaud, Raphael; Morris, Robert Harold; Abdur-Rashid, Kamaluddin
Patent: US2004/15017 A1, 2004 ;
Location in patent: Page 5 ;
反应条件
[(η5-pentamethylcyclopentadienyl)IrIIIbis-(κC-1,3-dimethylimidazol-2-ylidene)Cl]BF4; potassium hydroxide in isopropyl alcohol T=60°C; 5 h;
参考文献
ACS Catalysis, , vol. 4, # 3 p. 973 - 985
反应条件
[H(OEt2)2]+[[3,5-(CF3)2C6H3]4B]-; C32H63CoNP2Si; hydrogen in tetrahydrofuran T=60°C; P=760.051 Torr; 65 h; PressureTemperature; Overall yield = 100 percent;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 48 p. 12102 - 12106
Angew. Chem., , p. 12077
反应条件
lithium aluminium tetrahydride in 1,4-dioxane T=120°C; 15 h;
参考文献
Tetrahedron, , vol. 31, p. 383 - 389
反应条件
magnesium in diethyl ether 2 h; Ambient temperature;
参考文献
Pirrung, Frank O. H.; Hiemstra, Henk; Speckamp, W. Nico; Kaptein, Bernard; Schoemaker, Hans E.
Tetrahedron, 1994 , vol. 50, # 43 p. 12415 - 12442
反应条件
trimethylaluminum in hexane; dichloromethane T=0 - 25°C; Yield given. Yields of byproduct given;
参考文献
Chemistry Letters, , # 8 p. 817 - 818
反应条件
1: 1.) aq. 10 percent sodium hydroxide, 2.) conc. hydrochloric acid / 1.) reflux, 20 h, 2.) 0 deg C, pH 6 2: LAH / diethyl ether / 1 h / Ambient temperature View Scheme
参考文献
Tetrahedron, , vol. 49, # 4 p. 947 - 964
反应条件
1: With [RuH(CO)(dppp)(ampy)]Cl T=90°C; 0.0833333 h; Inert atmosphereSchlenk technique; 2: With sodium isopropanolate in isopropyl alcohol 5 h; Inert atmosphereSchlenk technique;
参考文献
Organometallics, , vol. 32, # 19 p. 5299 - 5304
反应条件
copper diacetate; iron(II) sulfate in acetic acid
参考文献
Tetrahedron, , vol. 35, p. 2021 - 2026
反应条件
copper diacetate in benzene Irradiation;
参考文献
Tetrahedron Letters, , p. 561 - 564
