1,2-二甲基-1,4-环己二烯合成路线 (共 17 条)
反应条件
propionic acid 1.) 80 deg C, 6 h, 2.) reflux, 4 h; various reagents in 2nd step; Product distribution;
参考文献
Zaidlewicz, Marek; Binkul, Jacek R.; Sokol, Wojciech
Journal of Organometallic Chemistry, 1999 , vol. 580, # 2 p. 354 - 362
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in acetic acid T=25°C; Rate constantMechanism;
参考文献
Thummel, Randolph P.; Cravey, Wesley E.; Cantu, David B.
Journal of Organic Chemistry, 1980 , vol. 45, # 9 p. 1633 - 1637
参考文献
Hueckel; Woerffel
Chemische Berichte, 1956 , vol. 89, p. 2098,2101
反应条件
1: 42 percent / Mg monoperoxyphthalate hexahydrate (MMPP) / ethanol / 3 h / Ambient temperature
2: 76 percent / Br2 / CHCl3 / -50 °C
3: potassium tert-butoxide / diethyl ether / 1 h / 0 °C
View Scheme
参考文献
Gillard, James R.; Newlands, Michael J.; Bridson, John N.; Burnell, D. Jean
Canadian Journal of Chemistry, 1991 , vol. 69, # 9 p. 1337 - 1343
反应条件
(aminomethyl) phosphonic acid; dihydrogen peroxide; sodium tungstate; [Me(n-C8H17)3N]HSO4 in water; toluene
T=70°C; Epoxidation; 1 h;
参考文献
Sato, Kazuhiko; Aoki, Masao; Ogawa, Masami; Hashimoto, Tadashi; Panyella, David; Noyori, Ryoji
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 4 p. 905 - 915
反应条件
MMPP in ethanol
3 h; Ambient temperature;
参考文献
Gillard, James R.; Newlands, Michael J.; Bridson, John N.; Burnell, D. Jean
Canadian Journal of Chemistry, 1991 , vol. 69, # 9 p. 1337 - 1343
参考文献
Hueckel; Woerffel
Chemische Berichte, 1955 , vol. 88, p. 338,345