1: barium hydroxide octahydrate / methanol / 4 d, -10 deg C; 10 h, RT 2: 1M potassium methoxide / methanol / 40 - 45 °C / electrolysis: anode: platinum foil; current source: galvanostat; current density 220 mA cm-2; current consumption: 1.25 F mol-1; cell voltage 40-70 V 3: hydroboration-oxidation 4: 1M potassium methoxide / methanol / 40 °C / electrolysis: anode: platinum foil; current source: galvanostat; current density 200 mA cm-2; current consumption: 3.03 F mol-1; cell voltage 50-60 V View Scheme
1: barium hydroxide octahydrate / methanol / 4 d, -10 deg C; 10 h, RT 2: 1M potassium methoxide / methanol / 40 - 45 °C / electrolysis: anode: platinum foil; current source: galvanostat; current density 220 mA cm-2; current consumption: 1.25 F mol-1; cell voltage 40-70 V 3: hydroboration-oxidation 4: 1M potassium methoxide / methanol / 40 °C / electrolysis: anode: platinum foil; current source: galvanostat; current density 200 mA cm-2; current consumption: 3.03 F mol-1; cell voltage 50-60 V View Scheme
参考文献
Weiper-Idelmann, Andreas; Aus Dem Kahmen, Martin; Schaefer, Hans J.; Gockeln, Marianne
Acta Chemica Scandinavica, 1998 , vol. 52, # 6 p. 672 - 682
1: barium hydroxide octahydrate / methanol / 4 d, -10 deg C; 10 h, RT
2: 1M potassium methoxide / methanol / 40 - 45 °C / electrolysis: anode: platinum foil; current source: galvanostat; current density 220 mA cm-2; current consumption: 1.25 F mol-1; cell voltage 40-70 V
3: hydroboration-oxidation
4: 42 percent / 1M potassium methoxide / methanol / 40 °C / electrolysis: anode: platinum foil; current source: galvanostat; current density 200 mA cm-2; current consumption: 3.03 F mol-1; cell voltage 50-60 V
View Scheme
参考文献
Weiper-Idelmann, Andreas; Aus Dem Kahmen, Martin; Schaefer, Hans J.; Gockeln, Marianne
Acta Chemica Scandinavica, 1998 , vol. 52, # 6 p. 672 - 682
