三(三苯基膦)羰基氢化铑合成路线 （共 18 条）
参考文献
Journal of Organometallic Chemistry, , vol. 246, # 1 p. 61 - 72
反应条件
1: isopropyl alcohol 2: isopropyl alcohol View Scheme
参考文献
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, , vol. 31, # 2 p. 121 - 131
反应条件
in methanol; dichloromethane byproducts: (C6H5)3PO; N2 atmosphere; addn. of N2H4*H2O in CH3OH/CH2Cl2 to the Rh complex; stirring for 3 h;; the pptd. hydrido complex was filtered off; pptn. of the hydrazine complex by addn. of n-hexane to the filtrate; filtration; washing with n-hexane; elem. anal.;;
参考文献
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, , vol. 20, # 7 p. 673 - 676
反应条件
in methanol; dichloromethane byproducts: (C6H5)3PO; N2 atmosphere; addn. of N2H4*H2O in CH3OH/CH2Cl2 to the Rh complex; stirring for 3 h;; the pptd. hydrido complex was filtered off; pptn. of the hydrazine complex by addn. of n-hexane to the filtrate; filtration; washing with n-hexane; elem. anal.;;
参考文献
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, , vol. 20, # 7 p. 673 - 676
反应条件
in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) (N2); addn. of a soln. of K-Rh complex in THF to a soln. of Rh complex in THF-d8, react. at room temp. for 24 h; NMR detection;
参考文献
Organometallics, , vol. 31, # 11 p. 4251 - 4258
反应条件
in not given H2-atmosphere; stirring Rh-complex with 4 equiv. PPh3 and 0.5 equiv. of PPh2(NC4H4) (in C6D6 or PhMe, not specified); not isolated, detd. by (1)H-, (31)P-NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 552, # 1-2 p. 159 - 164
反应条件
in benzene a mixt. of Rh-complex and Cl3CCOOH was stirred in benzene at ambient temp. for 30 min under N2; evapd. to near dryness, residue was treated with MeOH, washed with MeOHand hexane, dried in vac.;
参考文献
Boyar, Esther B.; Robinson, Stephen D.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 2113 - 2120
参考文献
Gmelin Handbook: Rh: SVol.B2, 2.1.1.5.3, page 102 - 103
