1,4,9,10-蒽四酮合成路线 （共 56 条）
参考文献
Dimroth; Schultze
Justus Liebigs Annalen der Chemie, 1916 , vol. 411, p. 349
反应条件
phosphorus pentachloride; nitrobenzene
参考文献
Barnett; Matthews; Wiltshire
Recueil des Travaux Chimiques des Pays-Bas, 1926 , vol. 45, p. 560
参考文献
Dimroth; Schultze
Justus Liebigs Annalen der Chemie, 1916 , vol. 411, p. 349
反应条件
in toluene 3 h; Heating;
参考文献
Tolstikov, G. A.; Shul'ts, E.E.; Safarova, G.M.; Spirikhin, L.V.; Panasenko, A.A.
Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 6 p. 1110 - 1119
Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 6 p. 1283 - 1296
反应条件
2: H2 / Pd
3: Na2CO3
View Scheme
参考文献
Lee; Martinez; Smith; Henry
Journal of Organic Chemistry, 1976 , vol. 41, # 13 p. 2296 - 2303
反应条件
1: 83 percent / conc. hydrochloric acid / acetic acid / 1 h / Ambient temperature
2: 84 percent / lead tetra-acetate / acetic acid / 1 h / Ambient temperature
3: 83 percent / conc. hydrochloric acid / acetic acid / 2 h / Ambient temperature
View Scheme
参考文献
Cano, Pilar; Farina, Francisco; Parellada, M. Dolores; Pascual, Conrado; Prados, Pilar
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1923 - 1928
反应条件
in xylene; benzene
4 h; Heating;
参考文献
Kimura, Yoshikazu; Suzuki, Michiyo; Matsumoto, Teruyo; Abe, Rumiko; Terashima, Shiro
Chemistry Letters, 1984 , p. 473 - 476
Title/Abstract Show Details
Kimura; Suzuki; Matsumoto; et al.
Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 2 p. 415 - 421
反应条件
1: 79 percent / benzene; xylene / 4 h / Heating
2: 91 percent / sodium acatate / acetic acid / 30 h / Heating
3: 98 percent / H2SO4 / 1.) 1 h.; 2.) rt. 3d.; 3.) AcOH, reflux, 2h.
4: 83 percent / HCl / ethanol; tetrahydrofuran; acetic acid / 1.) EtOH, THF, 0 deg C, 20 min.; 2.) AcOH, 0 deg C., 30 min; 3.) rt. overnight
5: 94 percent / HCl / acetic acid / 9 h / Heating
6: tetrahydrofuran; hexamethylphosphoric acid triamide / 18 h / Ambient temperature
7: 56 percent / trimethylsilyl triflate / tetrahydrofuran; hexamethylphosphoric acid triamide; diethyl ether / 1.) -20 deg C, 15 min.; 2.) -40 deg C, 2 h.; 3.) -40 deg C, 1 h.
View Scheme
参考文献
Kimura, Yoshikazu; Suzuki, Michiyo; Matsumoto, Teruyo; Abe, Rumiko; Terashima, Shiro
Chemistry Letters, 1984 , p. 473 - 476
反应条件
1: glacial acetic acid; bromine
2: diluted alcohol; sulfur dioxide
View Scheme
参考文献
Dimroth; Schultze; Heinze
Chemische Berichte, 1921 , vol. 54, p. 3047
反应条件
hydrogenchloride in acetic acid
1 h; Ambient temperature;
参考文献
Cano, Pilar; Farina, Francisco; Parellada, M. Dolores; Pascual, Conrado; Prados, Pilar
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1923 - 1928
