palladium diacetate; caesium carbonate; SIDip*HCl in N,N-dimethyl-formamide T=120°C; Suzuki coupling; 14 h;

1: With Rh2(OAc)4; 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride; sodium t-butanolate; tri-cyclo-hexyl-phosphine in toluene T=80°C; 2: With water Acidic conditions;

caesium carbonate; N,N'-di(2,4,6-trimethylphenyl)-4,5-dihydroimidazolinium chloride; palladium diacetate in 1,4-dioxane T=80°C; 16 h;

1: phenyl-magnesium bromide With ZnCl2*TMEDA in tetrahydrofuran T=0°C; Inert atmosphere; 2: 4-methoxy-N-(phenylmethylene)-benzenamine With iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl in tetrahydrofuran T=0°C; 48 h; Inert atmosphere; 3: With hydrogenchloride; water in tetrahydrofuran T=20°C; 3 h; chemoselective reaction;

hydrogenchloride in water T=20°C; 4 h;

1: phenyl-magnesium bromide With ZnCl2*TMEDA in tetrahydrofuran T=0°C; Inert atmosphere; 2: (2-chlorobenzylidene)(4-methoxyphenyl)amine With iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl in tetrahydrofuran T=0°C; 3 h; Inert atmosphere; 3: With hydrogenchloride; water in tetrahydrofuran T=20°C; 3 h;

1: bromobenzene With magnesium in tetrahydrofuran 1 h; Inert atmosphereReflux; 2: 1,3-dichloro-2-iodobenzene in tetrahydrofuran T=20°C; Inert atmosphereReflux; 3: formic acid ethyl ester in tetrahydrofuran 0.5 h; Inert atmosphereReflux;

1: phenyl-magnesium bromide With ZnCl2*TMEDA in tetrahydrofuran T=0°C; Inert atmosphere; 2: [1-(2-Bromo-phenyl)-meth-(E)-ylidene]-(4-methoxy-phenyl)-amine With iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl in tetrahydrofuran T=0°C; 3 h; Inert atmosphere; 3: With hydrogenchloride; water in tetrahydrofuran T=20°C; 3 h;

sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether 3 h; Heating;

1: With 1-methyl-pyrrolidin-2-one; potassium carbonate; triphenylphosphine; [Ru(II)(η6-benzene)(μ-Cl)Cl]2 T=120°C; 20 h; 2: Further stages.;