in diethylene glycol dimethyl ether byproducts: NaAlH4; pptn. on Et2O addn.;
参考文献
Bakum, S. I.; Kuznetsova, S. F.; Kuznetsov, N. T.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1994 , vol. 39, p. 549 - 550
Zhurnal Neorganicheskoi Khimii, 1994 , vol. 39, p. 576 - 577
in N,N-dimethyl-formamide byproducts: H3BO3, NaCl, HCl; NaBH4 added in small portions with vigorous stirring to soln. of RhCl3*3H2O, coagulated, formation of gaseous H2, ppt. separated from mother liqour; chem. anal.;
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 33, p. 698 - 700
Zhurnal Neorganicheskoi Khimii, , vol. 33, p. 1235 - 1238
in diethyl ether React. of starting materials in Et2O (vac. distd., -196°C), warming to 25°C, and stirring overnight.; Distn. of volatile materials into a -196°C U-trap and fractionalcondensation at -68 and -196°C yields Me3N*BH3 in the -68°C trap.;
参考文献
Gaines, Donald F.; Coons, Darrell E.
Inorganic Chemistry, 1986 , vol. 25, p. 364 - 367
byproducts: HI, I2; at 200°C, under N2; removing of I2: reaction mixt. dissolved in CS2, addn. of Zn or Hg, filtering, evapn. of solvent, sublimation in vac. twice;
参考文献
Schumb, W. C.; Gamble, E. L.; Danus, M. B.
Journal of the American Chemical Society, 1949 , vol. 71, p. 3225 - 3229
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Gmelin Handbook: B: SVol.1, 4.6, page 204 - 209
