反式-1-苯基-1,3-丁二烯合成路线 （共 179 条）
反应条件
Multistep reaction. Title compound not separated from byproducts;
参考文献
Canadian Journal of Chemistry, , vol. 58, p. 1144 - 1150
反应条件
tris(triphenylphosphine)ruthenium(II) chloride in benzene T=120°C; 17 h;
参考文献
Kamigata, Nobumasa; Fukushima, Takamasa; Terakawa, Yoshie; Yoshida, Masato; Sawada, Hideo
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 3 p. 627 - 633
反应条件
triethylamine; palladium diacetate; tris-(o-tolyl)phosphine T=100°C; 5 h;
参考文献
Mitsudo, Taki-aki; Fischetti, William; Heck, Richard F.
Journal of Organic Chemistry, 1984 , vol. 49, p. 1640 - 1646
反应条件
1: 1.) PdCl2((R)-N,N-dimethyl-1-<(S)-2-(diphenylphosphino)ferrocenyl>ethylamine) / 1.) RT, 1 h, 2.) RT, 22 h 2: H2 / 5percent Pd-C / ethanol / 760 Torr 3: KF, m-CPBA / dimethylformamide / 18 h / Ambient temperature View Scheme
参考文献
Ohmura, Hideaki; Matsuhashi, Hayao; Tanaka, Makoto; Kuroboshi, Manabu; Hiyama, Tamejiro; et al.
Journal of Organometallic Chemistry, 1995 , vol. 499, # 1.2 p. 167 - 172
反应条件
cobalt(III) acetate T=49.9°C; 6 h; MechanismProduct distribution;
参考文献
Morimoto, Takashi; Hirano, Masao; Enokida, Takashi; Isomoto, Akihito; Hamaguchi, Takayoshi; Zhung, Xumin
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1988 , p. 1531 - 1536
反应条件
2: palladium/charcoal / 300 °C
View Scheme
参考文献
McBee et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 3389
Journal of Organic Chemistry, 1956 , vol. 38, p. 632
反应条件
1: sulfur / 340 °C / 300 Torr
2: benzene; tin (IV)-chloride
3: amalgamated zinc; aqueous hydrochloric acid; acetic acid / Erhitzen des mit Toluol versetzten Reaktionsgemisches
4: phosphorus (V)-chloride; benzene / anschliessend mit Zinn(IV)-chlorid behandeln
5: acetic acid; amalgamated zinc; aqueous hydrochloric acid
6: sulfur / 250 °C
View Scheme
参考文献
Horton
Journal of Organic Chemistry, 1949 , vol. 14, p. 761,768
反应条件
1: hydroquinone / 72 h / 100 °C
2: 1) LDA; 2) O2; 3) SnCl2, aq. HCl; 4) aq. NaOH
View Scheme
参考文献
Freerksen, Robert W.; Selikson, Sandra J.; Wroble, Randall R.; Kyler, S. Keith; Watt, David S.
Journal of Organic Chemistry, 1983 , vol. 48, # 22 p. 4087 - 4096
反应条件
1,10-phenanthroline; palladium (II) trifluoroacetate; silver trifluoroacetate in toluene
T=130°C; 16 h;
参考文献
Lee, Wei-Chih; Wang, Ting-Hsuan; Ong, Tiow-Gan
Chemical Communications, 2014 , vol. 50, # 28 p. 3671 - 3673
