in further solvent(s) soln. of (Me2SnS)3 in BrCH2CH2Br was heated at 140°C for 35 h; excess C2H4Br2 was removed in vac. at room temp., products were sepd. by sublimation at 70°C; dithiane was identified by chromy., elem. anal. for 2Me2SnBr2*S(CH2CH2)2S;
参考文献
Shcherbakov, V. I.; Grigor'eva, I. K.; Razuvaev, G. A.; Zakharov, L. N.; Bochkova, R. I.; Struchkov, Yu. T.
Journal of Organometallic Chemistry, 1987 , vol. 319, p. 41 - 48
copper in neat (no solvent) byproducts: CuS; freshly precipitated copper; heated in a sealed evacuated ampul at 170°C for 6 h; liquid product collected at liquid nitrogen temp.;
参考文献
Shcherbakov, V. I.; Grigor'eva, I. K.; D'yachkovskaya, O. S.; Razuvaev, G. A.
Journal of General Chemistry USSR (English Translation), 1985 , vol. 55, p. 91 - 94
Zhurnal Obshchei Khimii, 1985 , vol. 55, p. 107 - 110
copper in [3.3.1]nonane byproducts: CuS; freshly precipitated copper; Cu, sulfide and nonane heated in a sealed evacuated ampul at 160°C for 40 h; liquid decanted, solid residue washed with nonane, solns. combined, solvent removed, GLC;
参考文献
Shcherbakov, V. I.; Grigor'eva, I. K.; D'yachkovskaya, O. S.; Razuvaev, G. A.
Journal of General Chemistry USSR (English Translation), 1985 , vol. 55, p. 91 - 94
Zhurnal Obshchei Khimii, 1985 , vol. 55, p. 107 - 110
in neat (no solvent) a mixt. of Sn sulfide and freshly pptd. Cu heating in a sealed tube for6 h at 170°C, liquid product distilling off; purified by distillation in vacuo;
参考文献
Razuvaev, G.A.; Shcherbakov, V.I.; Grigor'Eva, I.K.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 245 - 252
in neat (no solvent) Sn sulfide heating in 1,2-dibromoethane for 30 h at 140°C, solvent removing in vacuo; purified by sublimation in vacuo, identified by elem. anal.;
参考文献
Razuvaev, G.A.; Shcherbakov, V.I.; Grigor'Eva, I.K.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 245 - 252
in [3.3.1]nonane a mixt. of Sn sulfide and freshly pptd. Cu heating in nonane in a sealed evacuated tube for 40 h at 160°C, liquid product decanting off,solid washing with nonane, solvent removing from combined solns. at 30°C/1 torr; purified by distillation in vacuo;
参考文献
Razuvaev, G.A.; Shcherbakov, V.I.; Grigor'Eva, I.K.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 245 - 252
copper in [3.3.1]nonane byproducts: CuS; freshly precipitated copper; Cu, sulfide and nonane heated in a sealed evacuated ampul at 160°C for 40 h; liquid decanted, solid residue washed with nonane, solns. combined, solvent removed, GLC;
参考文献
Shcherbakov, V. I.; Grigor'eva, I. K.; D'yachkovskaya, O. S.; Razuvaev, G. A.
Journal of General Chemistry USSR (English Translation), 1985 , vol. 55, p. 91 - 94
Zhurnal Obshchei Khimii, 1985 , vol. 55, p. 107 - 110
in [3.3.1]nonane a mixt. of Sn sulfide and freshly pptd. Cu heating in nonane in a sealed evacuated tube for 40 h at 160°C, liquid product decanting off,solid washing with nonane, solvent removing from combined solns. at 30°C/1 torr; purified by distillation in vacuo;
参考文献
Razuvaev, G.A.; Shcherbakov, V.I.; Grigor'Eva, I.K.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 245 - 252
in further solvent(s) soln. of (Me2SnS)3 in BrCH2CH2Br was heated at 140°C for 35 h; excess C2H4Br2 was removed in vac. at room temp., products were sepd. by sublimation at 70°C; dithiane was identified by chromy., elem. anal. for 2Me2SnBr2*S(CH2CH2)2S;
参考文献
Shcherbakov, V. I.; Grigor'eva, I. K.; Razuvaev, G. A.; Zakharov, L. N.; Bochkova, R. I.; Struchkov, Yu. T.
Journal of Organometallic Chemistry, 1987 , vol. 319, p. 41 - 48
in neat (no solvent) Sn sulfide heating in 1,2-dibromoethane for 30 h at 140°C, solvent removing in vacuo; purified by sublimation in vacuo, identified by elem. anal.;
参考文献
Razuvaev, G.A.; Shcherbakov, V.I.; Grigor'Eva, I.K.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 245 - 252
