in diethyl ether
on redn. of Ge-compd. by LiAlH4 in anhyd. ether (according to Mazerolles, P. and Faucher, A. Bull. Soc. Chim. Fr., 1967, No. 6, 2134; J. Organomet. Chem., 1973, 63, 195);;
参考文献
Hamann, Sefton D.; Mazerolles, Pierre; Faucher, Alfreda; Manuel, Georges
Australian Journal of Chemistry, 1984 , vol. 37, # 1 p. 23 - 28
in diethyl ether
reaction at -40 to -30°C and boiling on reflux for 2 h;;
参考文献
Neumann, W. P.; Niermann, H.; Sommer, R.
Liebigs Annalen der Chemie, 1962 , vol. 659, p. 27 - 39
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.6, page 110 - 113
in diethyl ether
mixt. of reagents in ether stirred with reflux for 3 h, hydrolyzed withwater; org. layer dried over CaCl2, evapd., fractionally distd.; elem. anal.;
参考文献
Mochida, Kunio
Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 3 p. 796 - 801
in further solvent(s)
LiAlH4 in tetraglyme cooled to -10°C; degassed under vac.; CH2CHSnCl3 in tetraglyme slowly added; during and after the addition, high boiling compds. removed in trap (-80°C); vinylstannane condensed in second trap (-130°C);
in toluene
addition of ether to a mixture of C6F5GeBr3 and LiAlH4 in toluene; cooling at 0°C;;
参考文献
Bochkarev, M. N.; Maiorova, L. P.; Korneva, S. P.; Bochkarev, L. N.; Vyazankin, N. S.
Journal of Organometallic Chemistry, 1974 , vol. 73, p. 220 - 236
Full Text Show Details
Gmelin Handbook: F: PerFHalOrg.4, 4.2.1, page 165 - 169
