tris-(dibenzylideneacetone)dipalladium(0); sodium acetate in benzonitrile T=100°C; Heck reaction; 1 h; Microwave irradiation; stereoselective reaction;

[RhCl(η2:η2-cycloocta-1,5-diene)]2; 4-bromooctafluorobutanetriethoxysilane in N,N-dimethyl-formamide T=20°C; 0.5 h; Inert atmosphere;

1: 4-methoxy-6-vinyl-2H-pyran-2-one With sodium acetate; palladium diacetate in acetonitrile Heck-Matsuda reaction; 0.166667 h; 2: 3,4-(methylenedioxy)benzenediazonium tetrafluoroborate in acetonitrile Heck-Matsuda reaction;

tris-(dibenzylideneacetone)dipalladium(0); sodium acetate in benzonitrile T=100°C; Heck reaction; 1 h; Microwave irradiation; stereoselective reaction;

potassium acetate; 18-crown-6 ether 1.5 h; Ambient temperature;

potassium acetate; 18-crown-6 ether 1.5 h; Ambient temperature;

potassium acetate; 18-crown-6 ether 1.5 h; Ambient temperature;

Stage #1: <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '2349612', constants.ctx, '0')">boron trifluoride diethyl etherate</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br />0.0833333&nbsp;h;&nbsp;&nbsp;Cooling with ice;&nbsp;<br />Stage #2: <b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1209339', constants.ctx, '0')">tert.-butylnitrite</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br />T=0&deg;C;&nbsp;<br /> &nbsp;