三(乙腈)三羰基铬(0)合成路线 （共 15 条）
反应条件
in acetonitrile under N2; suspn. of Cr compd. in acetonitrile refluxed in the dark for 18 h; soln. cooled (ice bath); filtration; from filtrate, solvent removed to give crystals;
参考文献
Perez-Encabo, Alfonso; Perrio, Stephane; Slawin, Alexandra M. Z.; Thomas, Susan E.; Wierzchleyski, Adam T.; Williams, David J.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 6 p. 629 - 642
反应条件
hydrochloric acid in acetonitrile byproducts: Me4NCl; conc. aq. HCl was added dropwise under Ar to a soln. of Cr-complex in MeCN; reaction mixt. was concd. in vacuo, filtered through a Celite pad (standard airless ware techniques), the pad washed with MeCH, solvent was evapd. under reduced pressure;
参考文献
McNeese, Timothy J.; Cohen, Maurice B.; Foxman, Bruce M.
Organometallics, 1984 , vol. 3, p. 552 - 556
反应条件
acetonitrile in acetonitrile refluxing, 15 min; cooling to room temp.; evapn.;
参考文献
Rigby, James H.; Ateeq, Humy S.; Charles, Nelly R.; Cuisiat, Stephane V.; Ferguson, Mark D.; Henshilwood, James A.; Krueger, A. Chris; Ogbu, Cyprian O.; Short, Kevin M.; Heeg
Journal of the American Chemical Society, 1993 , vol. 115, # 4 p. 1382 - 1396
反应条件
in acetonitrile inert atmosphere; not isolated, detd. by (1)H-NMR spectroscopy;
参考文献
Yim, Hing W.; Tran, Linh M.; Dobbin, Ebern D.; Rabinovich, Daniel; Liable-Sands, Louise M.; Incarvito, Christopher D.; Lam, Kin-Chung; Rheingold, Arnold L.
Inorganic Chemistry, 1999 , vol. 38, # 9 p. 2211 - 2215
反应条件
in dichloromethane; acetonitrile N2; a solution of the starting complex in CH3CN was treated with HHSO3CF3in THF;; spectroscopic characterization;;
参考文献
Sellmann, Dieter; Wille, Monika; Knoch, Falk
Inorganic Chemistry, 1993 , vol. 32, p. 2534 - 2543
反应条件
in dichloromethane; acetonitrile N2; a solution of the starting complex in CH3CN was treated with HBF4 in THF;; spectroscopic characterization;;
参考文献
Sellmann, Dieter; Wille, Monika; Knoch, Falk
Inorganic Chemistry, 1993 , vol. 32, p. 2534 - 2543
反应条件
in dichloromethane; acetonitrile N2; a solution of the starting complex in CH3CN was treated with HCl in THF;; spectroscopic characterization;;
参考文献
Sellmann, Dieter; Wille, Monika; Knoch, Falk
Inorganic Chemistry, 1993 , vol. 32, p. 2534 - 2543
反应条件
(N2), 10 h at 80°C; IR;
参考文献
Wadepohl, Hubert; Buechner, Klaus; Herrmann, Michael; Pritzkow, Hans
Organometallics, 1991 , vol. 10, p. 861 - 871
反应条件
(N2), 10 h at 80°C; IR;
参考文献
Wadepohl, Hubert; Buechner, Klaus; Herrmann, Michael; Pritzkow, Hans
Organometallics, 1991 , vol. 10, p. 861 - 871
反应条件
benzene in hexane; benzene in presence of ((CH3)3SiNH)3 in boiling solvents;;
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.6.1.2.1.1, page 183 - 190
