(1R,3S,5R)-rel-6,6-二甲基-2-亚甲基-双环[3.1.1]庚烷-3-醇合成路线 （共 6 条）
反应条件
1: (i) NaH, (ii) /BRN= 471308/ 2: (i) O3, (ii) NaI 3: (i), (ii) H2, Pd-C View Scheme
参考文献
Carlson,R.G.; Pierce,J.K.
Journal of Organic Chemistry, 1971 , vol. 36, # 16 p. 2319 - 2324
反应条件
nickel T=70 - 100°C; Hydrogenation.Isolierung ueber das 2-Carboxy-benzoyl-Derivat;
参考文献
Schmidt; Schulz
Ber. Schimmel, 1934 , p. 97,98
Full Text Show Details
Schmidt
Chemische Berichte, 1944 , vol. 77/79, p. 544,549
Ber. Schimmel, p. 79,82
反应条件
aluminum oxide T=220°C; the reaction was carried out in the injection port of a gas chromatograph; different temperatures; Product distribution;
参考文献
Kobold, Uwe; Vostrowsky, Otto; Bestmann, Hans Juergen; Kubeczka, Karl Heinz
Liebigs Annalen der Chemie, 1987 , p. 557 - 560
反应条件
1: HBr / diethyl ether
2: AgOAc / acetic acid
3: aq. AgNO3, NaOH / ethanol
View Scheme
参考文献
Treibs,W. et al.
Justus Liebigs Annalen der Chemie, 1960 , vol. 634, p. 118 - 124
反应条件
aluminum oxide
T=220°C; the reaction was carried out in the injection port of a gas chromatograph; different temperatures; Product distribution;
参考文献
Kobold, Uwe; Vostrowsky, Otto; Bestmann, Hans Juergen; Kubeczka, Karl Heinz
Liebigs Annalen der Chemie, 1987 , p. 557 - 560
反应条件
1: 70 percent / HBr / diethyl ether / 0 °C
2: silver nitrate / acetic acid / 1 h / 40 °C
View Scheme
参考文献
Lopez, Luigi; Mele, Giuseppe; Fiandanese, Vito; Cardellicchio, Cosimo; Nacci, Angelo
Tetrahedron, 1994 , vol. 50, # 30 p. 9097 - 9106
