in 1,4-dioxane Kinetics; byproducts: HCl; addn. of suspn. of (Cl3PNPCl3)PCl6 in dioxane to HN(POCl2)2 in dioxane (molar ratio 1:1) dropwise during 1 h at ambient temp., standing (several days); various product ratio for various conditions; (31)P-NMR spectroscopic monitoring;

in water Kinetics; byproducts: HCl; dissolution of HN(POCl2)2 in water at 0°C, influence of NaOH studied; not isolated; (31)P-NMR;

in 1,4-dioxane Kinetics; byproducts: HCl; addn. of suspn. of (Cl3PNPCl3)PCl6 in dioxane to HN(POCl2)2 in dioxane (molar ratio 1:1) dropwise during 1 h at ambient temp., standing (several days); various product ratio for various conditions; (31)P-NMR spectroscopic monitoring;

in solid byproducts: HCl; (dry N2); ambient temp., react. time (several min), evolution of HCl gas; not isolated; detn. by (31)P-NMR spectroscopy;

in 1,4-dioxane Kinetics; byproducts: HCl; addn. of suspn. of (Cl3PNPCl3)PCl6 in dioxane to HN(POCl2)2 in dioxane (molar ratio 1:1) dropwise during 1 h at ambient temp., standing (several days); various product ratio for various conditions; (31)P-NMR spectroscopic monitoring;