乙酸(Z)-5-十二烯醇酯合成路线 （共 10 条）
反应条件
pyridine in benzene
T=20°C;
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
pyridine
24 h; Ambient temperature;
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
反应条件
1: 1.) sodiobis(trimethylsilyl)amide / 1.) THF, 50-55 deg C, 2.) -78 deg C; 20 deg C
2: 95 percent / HCl / H2O; acetone / 20 °C
3: 87 percent / LiAlH4 / diethyl ether / 20 °C
4: 85 percent / pyridine / benzene / 20 °C
View Scheme
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
1: 1.) sodiobis(trimethylsilyl)amide / 1.) THF, 50-55 deg C, 2.) -78 deg C; 20 deg C
2: 95 percent / HCl / H2O; acetone / 20 °C
3: 87 percent / LiAlH4 / diethyl ether / 20 °C
4: 85 percent / pyridine / benzene / 20 °C
View Scheme
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
2: lithium aluminium hydride / diethyl ether / 3 h / Ambient temperature
3: 96 percent / pyridine / 24 h / Ambient temperature
View Scheme
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
反应条件
1: triethylamine / CH2Cl2 / 1) 0 deg C, 0.5 h, 2) RT, 6 h
2: LiBr / acetone / 5 h / Ambient temperature
3: 73 percent / dimethylsulfoxide / Ambient temperature
4: KOH / ethane-1,2-diol / 6 h / Heating
6: lithium aluminium hydride / diethyl ether / 3 h / Ambient temperature
7: 96 percent / pyridine / 24 h / Ambient temperature
View Scheme
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
反应条件
1: 73 percent / dimethylsulfoxide / Ambient temperature
2: KOH / ethane-1,2-diol / 6 h / Heating
4: lithium aluminium hydride / diethyl ether / 3 h / Ambient temperature
5: 96 percent / pyridine / 24 h / Ambient temperature
View Scheme
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
反应条件
1: KOH / ethane-1,2-diol / 6 h / Heating
3: lithium aluminium hydride / diethyl ether / 3 h / Ambient temperature
4: 96 percent / pyridine / 24 h / Ambient temperature
View Scheme
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
反应条件
1: lithium aluminium hydride / diethyl ether / 3 h / Ambient temperature
2: 96 percent / pyridine / 24 h / Ambient temperature
View Scheme
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
反应条件
1: LiBr / acetone / 5 h / Ambient temperature
2: 73 percent / dimethylsulfoxide / Ambient temperature
3: KOH / ethane-1,2-diol / 6 h / Heating
5: lithium aluminium hydride / diethyl ether / 3 h / Ambient temperature
6: 96 percent / pyridine / 24 h / Ambient temperature
View Scheme
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
