1,2:5,6-二-O-异亚丙基-alpha-D-呋喃葡萄糖S-甲基二硫代碳酸酯合成路线 （共 12 条）
反应条件
1: carbon disulfide; diacetone-α-D-glucose With 1H-imidazole; sodium hydride in tetrahydrofuran T=20°C; Addition; 0.5 h; 2: methyl iodide in tetrahydrofuran T=20°C; Methylation; 0.5 h; Further stages.;
参考文献
Togo, Hideo; Matsubayashi, Sou; Yamazaki, Osamu; Yokoyama, Masataka
Journal of Organic Chemistry, 2000 , vol. 65, # 9 p. 2816 - 2819
反应条件
carbon disulfide in tetrahydrofuran
参考文献
Schering Corporation
Patent: US4078139 A1, 1978 ;
反应条件
1: NaH; imidazole View Scheme
参考文献
Bomholt, Niels; Jorgensen, Per T.; Pedersen, Erik B.
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 24 p. 7376 - 7378
反应条件
1: 85percent H3PO4, ZnCl2 / 18 h / Ambient temperature 2: 1.) NaH View Scheme
参考文献
Hwang, Seong Woo; Adiyaman, Mustafa; Khanapure, Subhash; Schio, Laurent; Rokach, Joshua
Journal of the American Chemical Society, 1994 , vol. 116, # 23 p. 10829 - 10830
参考文献
Bomholt, Niels; Jorgensen, Per T.; Pedersen, Erik B.
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 24 p. 7376 - 7378
参考文献
Granata, Alessandro; Perlin, Arthur S.
Carbohydrate Research, 1981 , vol. 94, p. 165 - 172
反应条件
carbon disulfide; diethyl ether Behandeln des Reaktionsprodukts mit Methyljodid;
参考文献
Sanyal; Purves
Canadian Journal of Chemistry, 1956 , vol. 34, p. 426,432
Full Text Show Details
Freudenberg; Wolf
Chemische Berichte, 1927 , vol. 60, p. 232,238
反应条件
1: tri-n-butyl-tin hydride / toluene / |Reflux 2: sulfuric acid / water / 1 h / |Reflux 3: sodium hydroxide; oxygen; catalase / water / 5 h / 25 °C / pH 7.0 / |Enzymatic reaction View Scheme
参考文献
Pfeifer, Yvonne V.; Haase, Paul T.; Kroh, Lothar W.
Journal of Agricultural and Food Chemistry, 2013 , vol. 61, # 12 p. 3090 - 3096
反应条件
1: tri-n-butyl-tin hydride / toluene / |Reflux 2: sulfuric acid / water / 1 h / |Reflux 3: sodium hydroxide; oxygen; catalase / water / 5 h / 25 °C / pH 7.0 / |Enzymatic reaction 4: oxygen; hydrogenchloride / water / 5 h / 130 °C / pH 5 / |Sealed tube View Scheme
参考文献
Pfeifer, Yvonne V.; Haase, Paul T.; Kroh, Lothar W.
Journal of Agricultural and Food Chemistry, 2013 , vol. 61, # 12 p. 3090 - 3096
反应条件
2,2'-azo-bisisobutyronitrile; hypophosphorous acid; triethylamine in 1,4-dioxane 0.75 h; Heatingother substrates, other base, other times, also with dimethyl phosphite;
参考文献
Tetrahedron Letters, , vol. 33, # 39 p. 5709 - 5712
