二(2-甲基-2-丙基)锌合成路线 （共 13 条）
反应条件
in diethyl ether; pentane byproducts: LiCl; (Ar); std. Schlenk technique; soln. of BuLi in pentane was added over 1 h to soln. of ZnCl2 in Et2O at 0°C; slowly warmed to room temp.; stirred for 1 h; filtered through Celite; solvent removed (vac.); sublimed under partial vac. at room temp.;
参考文献
Sarazin, Yann; Wright, Joseph A.; Harding, Duncan A.J.; Martin, Eddy; Woodman, Timothy J.; Hughes, David L.; Bochmann, Manfred
Journal of Organometallic Chemistry, 2008 , vol. 693, # 8-9 p. 1494 - 1501
反应条件
in benzene-d6 Kinetics; stirred for a few min, left standing in NMR tube at 22°C for 1 h; reversible reaction; not isolated; (1)H NMR spectral data;
参考文献
Tang, Hui
Organometallics, 2000 , vol. 19, # 23 p. 4810 - 4819
反应条件
in benzene-d6 Kinetics; stirred for a few min, left standing in NMR tube at 22°C for 1 h; reversible reaction; not isolated; (1)H NMR spectral data;
参考文献
Tang, Hui
Organometallics, 2000 , vol. 19, # 23 p. 4810 - 4819
反应条件
in neat (no solvent) Kinetics; byproducts: butene; thermal decompn. (452-505 K, sealed ampul); chromy.;
参考文献
Sokolovskii, A. E.; Baev, A. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 2093 - 2098
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 2336 - 2342
反应条件
in neat (no solvent) Kinetics; byproducts: butene; thermal decompn. (452-505 K, sealed ampul); chromy.;
参考文献
Sokolovskii, A. E.; Baev, A. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 2093 - 2098
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 2336 - 2342
反应条件
(CuOTf)2.C6H6 in tetrahydrofuran T=25°C; 1 h;
参考文献
Herman, Ashley M.; Johnson, Jeffrey S.
Journal of Organic Chemistry, 2006 , vol. 71, # 1 p. 219 - 224
反应条件
bis-(pyridin-2-yl)amine; n-butyl-sodium in hexane T=20°C; 18 h; Inert atmosphereSchlenk techniqueReflux;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 28 p. 7190 - 7193
Angew. Chem., , vol. 125, # 28 p. 7331 - 7334,4
反应条件
in hexane 18 h; Inert atmosphereSchlenk techniqueReflux; Reagent/catalyst;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 28 p. 7190 - 7193
Angew. Chem., , vol. 125, # 28 p. 7331 - 7334,4
反应条件
in neat (no solvent) Kinetics; byproducts: butene; thermal decompn. (452-505 K, sealed ampul); chromy.;
参考文献
Sokolovskii, A. E.; Baev, A. K.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 2093 - 2098
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 2336 - 2342
反应条件
bis-(pyridin-2-yl)amine; n-butyl-sodium in hexane T=20°C; 18 h; Inert atmosphereSchlenk techniqueReflux;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 28 p. 7190 - 7193
Angew. Chem., , vol. 125, # 28 p. 7331 - 7334,4
