2,2-二氯-1,1,1,3,3,3-六氟丙烷合成路线 （共 67 条）
反应条件
hydrogen fluoride; chlorine; copper-substituted α-chromium oxide (99percent chromium/1percent copper) treated with HF
T=375°C; P=760.051 Torr; 0.00138889 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen fluoride; chlorine; Cr(NO3)3/Zn(NO3)2 95/5 calcined at 900 C
T=280 - 320°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;
反应条件
hydrogen fluoride; catalyst from preparation example 4 (98percent Cr/2percent Cu)
T=280 - 320°C; P=760.051 Torr; 0.00138889 h; Gas phase; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2007/19357 A1, 2007 ;
Location in patent: Page/Page column 12-14 ;
反应条件
hydrogen fluoride; chlorine; copper-substituted α-chromium oxide (98percent chromium/2percent copper) treated with HF
T=280°C; P=760.051 Torr; 0.00138889 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen fluoride; Cr(NO3)3[9(H2O)]; AgNO3; calcined
T=300 - 400°C; 0.00416667 - 0.00494444 h; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Sievert, Allen Capron
Patent: US2008/207963 A1, 2008 ;
Location in patent: Page/Page column 8-9 ;
反应条件
hydrogen fluoride; chlorine; copper-substituted α-chromium oxide (99percent chromium/1percent copper) treated with HF
T=280°C; P=760.051 Torr; 0.00138889 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen fluoride; chlorine; cobalt(II) chromite in nitrogen
T=375°C; P=760.051 Torr; 0.00416667 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2004/18397 A1, 2004 ;
Location in patent: Page 23; 25 ;
反应条件
hydrogen fluoride; chlorine
T=280°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;
反应条件
chlorine in water
Irradiation;
参考文献
Miller,W.T. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 3091 - 3099
反应条件
fluorine
T=175°C; 9.1 h;
参考文献
Bishop,B.C. et al.
Journal of the American Chemical Society, 1964 , vol. 86, p. 1827 - 1830
